By Dr Sunil E Fernando

The natural rubber tree converts a greenhouse gas to a hydrocarbon. It is also capable of delivering it in commercially viable quantities almost on a daily basis, unlike any other. In addition, it retains some carbohydrates produced over a 30-year period, as medium density hardwood. This natural process of the biosynthesis of two products not only sustains the farmer, but also reduces the impact on global warming to some extent due to carbon dioxide extraction. Thus, preserving existing rubber plantations and cultivating more, especially in marginal lands, will help to mitigate an imbalance created due to the production of excessive quantities of a greenhouse gas

Benefits of Growing Rubber: Hevea brasiliensis or the rubber tree began its epic journey in 1875, when Sir Henry Wickham brought 70,000 seeds from Rio Tapajos in the upper Amazon to Kew gardens in London. Of these, 1911 seedlings were planted in Gampaha botanical gardens, Sri Lanka, initiating an agricultural revolution in South East Asia and an industrial revolution globally. Apart from giving 14 million tons of Natural Rubber (NR) consumed annually worldwide, the tree has other attributes listed below.

 Extracting 24.9 kilograms of Carbon dioxide (CO2) Greenhouse gas (GHG) to produce one Kilogram of latex

 Yielding 2.1 cubic meters/tree of wood from GHG as biomass, every 30-year cycle

 Produce easily biodegradable litter, compared to monocultures like Teak

 Require less chemical fertilisers, water and pesticides

 Retains biodiversity as a tropical plant and co-exists with other species allowing for intercropping

The uniqueness of the rubber tree is its ability to fix CO2 almost instantaneously into a hydrocarbon on a daily basis, with water and energy from sunlight while nature took millions of years converting biomass to a hydrocarbon, Petroleum. The tree is a natural solar panel trapping energy from the Sun, propagating a chemical reaction giving a hydrocarbon, while releasing Oxygen to the atmosphere and accumulating a timber resource. Tapped from year 5, the tree removes a GHG every other day, unlike any other plant species, for 11 months of the year for 25 years.

Why Excess CO2 is bad

CO2 present in the atmosphere is a double-edged sword. "CO2-Earth" reports, its concentration increased from 330 ppm in 1975 to 408.55 in September 2019, and further to 410.27 in November 2019. CO2 absorbs Infrared radiation (heat radiation) from the Sun through molecular vibrations, and emit this energy unlike gases like Nitrogen and Oxygen. Ozone, Methane and Nitrous Oxide are other GHG's, which absorb energy from the sun and similarly emit heat, warming the atmosphere.

However, GHG's maintains atmospheric temperatures without converting Earth into an ice ball. Nevertheless, high concentration of GHG in atmosphere, emit more heat to sustain global warming due to an imbalance created by excessive human activity like burning fuel, rearing of cattle/sheep, giving-off excessive CO2 and Methane, respectively. Two confirmed methods to lower ill effects of GHG are, produce less and increase plant cover.

CO2 is the raw materials for all forms of Carbohydrates, Proteins and Fats produced by plants providing for growth and energy in life forms. What is alarming is the excess CO2 produced, accumulating in the atmosphere, and in Oceans. Dissolved CO2 in seawater, raises temperature and forms Carbonic acid, increasing Ocean acidification. Ocean acidification reduces the ability of sea creatures to fix Calcium as Calcium Carbonate, another form of Carbon sink.

Carbon Dioxide Accumulation Antoine Lavoisier said, in a chemical reaction matter is neither created nor destroyed. Producing GHG through human intervention, new matter is not created but it leads to an unsustainable imbalance of matter in the environment. This is what causes the problem.

Figure 1. Figure 1. Representation of the CO2 Cycle (https://serc.carleton.edu/eslabs/carbon/2a.html)

CO2 is a GHG not only produced by burning fuels and biomass. Humans exhale One Kilogram of it daily. Increase in population does not increase CO2, as exhaled balances out by inhaling. But when human population went up from 1 billion 200 years ago to 7 billion now, increase in human activity led to an imbalance in the atmosphere and the Oceans due to release of CO2 and Methane. Biomass generation too is dwindling due to the population pressure. Thus, this imbalance of accumulating matter capable of absorbing heat is the main reason for global warming.

Biosynthesis of Natural Rubber About 2000 plant species produce NR, but Hevea brasiliensis produce commercially exploitable dispersion in water as latex. The biological reason for NR production is not clear, but it may prevent pathogenic microorganisms entering the tree. Latex is found in horizontally arranged interconnected cells called laticifer, in the bark of the tree, High yielding plantations with about 400 trees per hectare have reported a production of 2500 Kg/NR /Year. The theoretical yield potential is estimated at, 7,000 to 10,000 kg/Ha/Year. A tree giving 15 to 30g of rubber per day, tapping on alternative days yields 2.2-4.5 Kg of NR per year. According to Apollo Vredestein R and D, on average 1.9 Kg of NR goes into a tire and a tree produces enough rubber to make 2 tires per year or 50 in lifetime.

Plants take in CO2 for survival. Some converts part into an edible form, as carbohydrate and fats while the rest is converted to forms like cellulose. These may end up as wood, becoming a Carbon sink for a length of time. In rubber trees, the process extends converting part of CO2 to a rubber hydrocarbon containing Carbon and Hydrogen, more akin to Petroleum. This wonder tree makes a hydrocarbon in few minutes, while nature took millions of years to convert biomass derived from CO2 to Petroleum.

The biosynthetic pathway for NR in Hevea begins with the monomer precursor, Isopentenyl pyrophosphate (IPP). IPP is an adduct of Pyrophosphoric acid and Isoprene monomer. However, IPP is not an uncommon material, limited to Hevea, but is formed from carbohydrates, in other plants, algae, bacteria, in mammals and humans. The formation of IPP is said to occur by following two pathways; Mevalonate (MVA) or non-mevalonate (non-MVA), deoxy-xylulose pathway. In rubber trees, breakdown products from carbohydrates like Pyruvates and Glyceraldehydes are transformed into IPP, in Cytosol in Cytoplasm/Plastids in plant cells, in several stages in the presence of many enzymes like mevalonate kinase (MVK) and mevalonate diphosphate decarboxylase (MVD). Figure 2.

Figure 2 Representation of the Formation of IPP through MVA and Non-MVA Pathways (Chiang. C. C. K, 2013, PhD Thesis, the Graduate Faculty of the University of Akron).

On isomerisation with enzyme, Isomerase IPP is converted to Dimethyl allyl pyrophosphate (DMPP). IPP and DMPP are building blocks for diverse groups of bio-molecules like Cholesterol, Vitamin K, Coenzyme Q10 (CoQ10) and Cis-polyisoprene (NR). Figure 3

Figure 3 Pathway to NR Biosynthesis

In rubber producing Russian dandelion (Taraxacum koksaghyz Rodin), enzyme transformation of sugars enrich NR formation. In the summer months, dandelions produce excess sugars and store it as Inulin. The possibility of metabolic engineering assisted enzyme degradation of Inulin to enhance production of IPP and then to NR has been explored for dandelion. Meanwhile Researchers have succeeded in decoding the Genome sequence in Hevea. This can lead to high yielding rubber clones, by locating genes responsible for biosynthesis of rubber.

Latex with 30% NR and 5% non-rubbers is produced in special cells called laticifers located horizontally and a lateral cut of the bark exposes most number, giving latex. Since the laticifer density is genotype dependant determining latex yield, it can give the direction for biologists as a selection marker for high yielding clones. In older rubber trees chemicals inducing Ethylene formation in the bark-tissue or generated it in situ like 2-Chloroethylphosphonic acid, are used as yield stimulants. Such developments, together with appropriate nutrition infusion, can increase NR yields, making rubber cultivation attractive to farmers.

Chloroethylphosphonic acid

Hevea brasiliensis is a dual-purpose tree, making Carbon sinks from CO2 in two ways, as a hydrocarbon and as wood, extracted in a 30-year cycle. Plants like wheat and rice also fix CO2 to give edible Carbohydrates, often twice a year. Nevertheless, human/animal consumption of edible carbohydrates quickly gives CO2 back to the environment. Thus with respect to environmental benefits, producing NR by growing rubber trees is a more favourable option. Fortunately, rubber cultivation has increased from 9.9 in 1975 to 14.0 million hectares in 2018 giving these benefits worldwide.

Preserving and enhancing rubber cultivation

The rubber farmer does a silent service by extracting latex and thus removing substantial quantity of GHG on a daily basis. As NR based products stay longer in service, Carbon in it remains intact for a longer period without burdening the environment. Each tree has the uncanny ability to function as a tap, working 150 days a year to clean up the environment unlike other plant-based options. It leaves a raw material as timber derived from GHG, extracted in every 30-year cycle giving 50 Kg of wood/tree. The global potential for wood at a replanting rate of 3% of acreage annually is, approx 7.30 Mn Tons/ year.

The environmental benefits can be maximised if the farmer taps the tree every other day for 11 months of the year if their livelihood is secularly safeguarded. Going into alternatives for from existing land is counterproductive to the environment. The negative process will occur only if the farmer finds the daily sustenance by growing rubber becomes a hard task. To encourage the farmer, requires a collective and a concerted effort from:

 Buyers giving stable/reasonable price

 Biologists developing fast growing, high yielding, drought and disease resistant trees

 Cultivation experts developing new and less-laborious extraction techniques and attractive intercropping practices

 Technologists adding value to existing NR products and developing new products

• Chemists by modification to give new elastomeric materials from NR as raw materials for other processes

• Environmentalists by increasing international awareness of the benefits of growing rubber

With respect to increased appreciation of the capability of modified NR forms, an enterprising tire manufacturer uses Epoxidised NR/Silica combination in automobile tire treads, to give higher wet grip and low rolling resistance tires. Such greener tires used in hybrid and electric cars, made these vehicles more environmental friendly. Olefinic elastomers like NR, contains reactive double bonds with potential to be modified as raw materials in many applications. Table 1, Figures 4 and 5. Such developments will give impetus to the sustainability and growth of an industry, benefitting the rubber farmer while fixing more GHG as well.

 

 

 

 

 

 

 

 

 

 

ENDS

References:

1. Bhowmik. I (2006), Tripura Rubber Mission Technical Bulletin 2. https://www.co2.earth/

3. Rao. P. S, et.al (1998), Agricultural and Forest Meteorology 3, 90

4. Chiang. C. C. K (2013), Natural rubber biosynthesis, PhD Thesis, The Graduate Faculty of The University of Akron, USA 5. Decoding the rubber tree genome, https://www.sciencedaily.com/releases/2016/06/160624100225.htm

 

 

Dr Sunil E Fernando is Former Executive Director, DPL Group, Sri Lanka, Managing Director Dipped Products (Thailand) Limited, Former Director, DPL Plantations and Kelani Valley Plantations Limited, Sri Lanka, and a Consultant - Latex Products

Flexsys has created what it says is the tyre industry’s first practical and scalable alternative to 6PPD, marking a major step toward replacing a chemical used for decades but now under regulatory pressure.

The company said the new antidegradant is the result of several years of research and testing with federal laboratories, independent scientific groups and tyre makers. Early results show the material could match the performance and safety of 6PPD while avoiding the environmental risks linked to 6PPD-quinone, a transformation product identified in 2020.

Flexsys said the new chemistry provides the short- and long-term protection needed to stop tyres cracking or ageing. It is also designed to fit into existing rubber compounds with minimal changes, which could help manufacturers adopt it quickly. The company added that the product meets environmental and regulatory benchmarks, including criteria set by the Washington State Department of Ecology.

Importantly, the new molecule is not part of the “PPD” family, meaning it does not form quinone during use. Flexsys said this would remove the environmental impact associated with 6PPD-quinone. The company is also using many of the same intermediate chemicals already used in 6PPD production. This could allow manufacturers to rely on existing factory assets and speed the shift to the new technology.

“This achievement reflects our unwavering commitment to responsible innovation, built on decades of expertise in tire protection chemistry,” said Carl Brech, Chief Executive Officer of Flexsys. “Our solution is formulated to deliver the performance and reliability that tire makers expect and is designed for future environmental and regulatory standards.”

6PPD has been essential to tyre durability for 50 years. But studies published in 2020 showed that 6PPD-quinone could harm aquatic species, including coho salmon. Regulators and tyre producers have been looking for a safer option since then. Flexsys said its new antidegradant meets this challenge without reducing tyre safety.

“Our team set out to develop a next-generation antidegradant that meets the tire industry’s highest performance standards without compromising tire safety, while also reducing toxicity,” said Neil Smith, Chief Technology and Sustainability Officer. “I could not be more proud of the perseverance and dedication of the Flexsys R&D team. Our group has been highly motivated by both the technical challenges of this project as well as the positive societal impact that this work will ultimately have.”

Flexsys acknowledged support from the Sustainable Polymers Tech Hub in Akron, Ohio, part of the U.S. EDA Tech Hubs programme.

The company is now working on process optimisation to allow large-scale production. It is also in discussions with regulators around the world to secure approvals for commercial use. Testing with tyre makers is continuing.

“Flexsys is helping set the direction of the tire industry for the coming decades with this development,” Brech said. “We will continue to work tirelessly to bring this breakthrough to the market as soon as possible.”

Wacker Chemie AG has strengthened its position in China’s fast-growing market for silicone specialities by opening a new application development centre with joint-venture partner SICO Performance Material in the eastern city of Jining.

The 2,300-square-metre facility brings together several laboratories focused on organofunctional silanes, which are used as high-performance additives in plastics, coatings and adhesives. By locating the centre next to SICO’s production and scale-up lines, Wacker aims to shorten development cycles and move new products into the market more quickly. The companies said investment in the site is in the mid-six-figure euro range.

Tom Koini, who leads Wacker’s silicones division, said the opening marks an important step in its China strategy. “As a provider of innovative silicone specialties and solutions, we can use this development center to achieve a key milestone for our business in China. Our focus is on high-margin specialty silanes, for which demand in China is rising continuously. This investment together with our partner SICO strengthens our presence and commitment to the region,” he said.

Wacker, which took a majority stake in SICO in 2022, is seeking to build a larger share of China’s specialty chemicals market, where demand for hybrid polymers has increased for years. These materials help improve the mechanical and chemical properties of adhesives, sealants, coatings and engineered plastics, all of which are used in sectors such as electric mobility, electronics and power equipment.

At the opening ceremony, SICO General Manager Kevin Qu called the centre an investment in the long term. “We can now pool all of our silane expertise here at our application development centre. This know-how ranges from chemical product properties and supply chain matters through to questions of process engineering and current marketing trends. We will leverage this in-depth knowledge to develop forward-looking innovations for our customers. This marks a new chapter of success in the history of our joint venture,” he said.

The companies said the centre will act as a link between research, technical service and manufacturing teams. Scientists will focus on developing additives, adhesion promoters and stabilisers based on organofunctional silanes and functional silicone fluids.

The Association of Natural Rubber Producing Countries (ANRPC) has released its Monthly NR Statistical Report for October 2025, providing an overview of key developments in the global natural rubber sector.

According to the report, the global natural rubber market in October was characterised by a distinct bearish trend in pricing. This decline can primarily due to a significant surge in production and export activities, which were initially stimulated by the higher prices seen earlier in the year. Meanwhile, overall demand has remained relatively subdued.

Looking ahead to the full year, projections indicate a modest 1.3 percent increase in global production for 2025, a figure that follows a recent downward revision for Indonesia. On the demand side, consumption is anticipated to grow by a slight 0.8 percent, influenced by an upward adjustment to Indonesia's consumption data. Despite the current price pressures, market sentiment shows some mixed signs of improvement, particularly within the tyre trade of certain specific markets.

DuPont commenced construction on a new MOLYKOTE speciality lubricants production facility in Zhangjiagang, Jiangsu Province, East China, on 18 November 2025 with a groundbreaking ceremony that was attended by Senior DuPont leadership from the MOLYKOTE business and the Asia-Pacific region, alongside government officials and key customers. This strategic investment, situated within the Yangtze River International Chemical Industrial Park, is projected to be fully operational by the beginning of 2027. The initiative is a key component of the brand's global expansion, designed to significantly enhance its responsiveness to regional market needs and foster local innovation.

The new plant will primarily focus on meeting the robust and growing demand for advanced lubricant solutions across several critical sectors in China, including transportation, industrial manufacturing, energy and electronics. By establishing a local manufacturing presence, DuPont aims to create a dynamic platform for collaboration with regional customers. This will enable the company to deliver next-generation lubricants with greater speed, precision and agility, ultimately shortening lead times and strengthening supply chains.

The MOLYKOTE brand, with a legacy spanning over 75 years, is globally recognised for its expertise in solving complex lubrication challenges and improving energy efficiency. Its comprehensive product portfolio, which includes greases, oils, anti-friction coatings and pastes, serves the automotive and industrial maintenance, repair and overhaul markets worldwide. Supported by a global network of manufacturing and research facilities, the brand continues to build on its reputation for performance and reliability.

Eugenio Toccalino, Vice President and General Manager, DuPont MOLYKOTE, said, “Today’s groundbreaking is the beginning of a new chapter in our journey to better serve our customers in China, innovate faster and to be a partner of choice for solving wear and friction challenges across industries. This facility will boost local capabilities for application and new formulation development, empowering customer collaboration and response in real time.”

Yi Zhang, Global VP and Regional President, DuPont Asia Pacific, said, “We are thrilled to be breaking ground on the MOLYKOTE China production facility in Zhangjiagang. This manufacturing unit will enable us to address current needs and future trends for speciality lubricants. It reflects our confidence in the long-term potential of customers in China and Asia-Pacific region and reinforces our commitment to deliver faster, more resilient and locally tailored solutions.”