By Dr Sunil E Fernando

The natural rubber tree converts a greenhouse gas to a hydrocarbon. It is also capable of delivering it in commercially viable quantities almost on a daily basis, unlike any other. In addition, it retains some carbohydrates produced over a 30-year period, as medium density hardwood. This natural process of the biosynthesis of two products not only sustains the farmer, but also reduces the impact on global warming to some extent due to carbon dioxide extraction. Thus, preserving existing rubber plantations and cultivating more, especially in marginal lands, will help to mitigate an imbalance created due to the production of excessive quantities of a greenhouse gas

Benefits of Growing Rubber: Hevea brasiliensis or the rubber tree began its epic journey in 1875, when Sir Henry Wickham brought 70,000 seeds from Rio Tapajos in the upper Amazon to Kew gardens in London. Of these, 1911 seedlings were planted in Gampaha botanical gardens, Sri Lanka, initiating an agricultural revolution in South East Asia and an industrial revolution globally. Apart from giving 14 million tons of Natural Rubber (NR) consumed annually worldwide, the tree has other attributes listed below.

 Extracting 24.9 kilograms of Carbon dioxide (CO2) Greenhouse gas (GHG) to produce one Kilogram of latex

 Yielding 2.1 cubic meters/tree of wood from GHG as biomass, every 30-year cycle

 Produce easily biodegradable litter, compared to monocultures like Teak

 Require less chemical fertilisers, water and pesticides

 Retains biodiversity as a tropical plant and co-exists with other species allowing for intercropping

The uniqueness of the rubber tree is its ability to fix CO2 almost instantaneously into a hydrocarbon on a daily basis, with water and energy from sunlight while nature took millions of years converting biomass to a hydrocarbon, Petroleum. The tree is a natural solar panel trapping energy from the Sun, propagating a chemical reaction giving a hydrocarbon, while releasing Oxygen to the atmosphere and accumulating a timber resource. Tapped from year 5, the tree removes a GHG every other day, unlike any other plant species, for 11 months of the year for 25 years.

Why Excess CO2 is bad

CO2 present in the atmosphere is a double-edged sword. "CO2-Earth" reports, its concentration increased from 330 ppm in 1975 to 408.55 in September 2019, and further to 410.27 in November 2019. CO2 absorbs Infrared radiation (heat radiation) from the Sun through molecular vibrations, and emit this energy unlike gases like Nitrogen and Oxygen. Ozone, Methane and Nitrous Oxide are other GHG's, which absorb energy from the sun and similarly emit heat, warming the atmosphere.

However, GHG's maintains atmospheric temperatures without converting Earth into an ice ball. Nevertheless, high concentration of GHG in atmosphere, emit more heat to sustain global warming due to an imbalance created by excessive human activity like burning fuel, rearing of cattle/sheep, giving-off excessive CO2 and Methane, respectively. Two confirmed methods to lower ill effects of GHG are, produce less and increase plant cover.

CO2 is the raw materials for all forms of Carbohydrates, Proteins and Fats produced by plants providing for growth and energy in life forms. What is alarming is the excess CO2 produced, accumulating in the atmosphere, and in Oceans. Dissolved CO2 in seawater, raises temperature and forms Carbonic acid, increasing Ocean acidification. Ocean acidification reduces the ability of sea creatures to fix Calcium as Calcium Carbonate, another form of Carbon sink.

Carbon Dioxide Accumulation Antoine Lavoisier said, in a chemical reaction matter is neither created nor destroyed. Producing GHG through human intervention, new matter is not created but it leads to an unsustainable imbalance of matter in the environment. This is what causes the problem.

Figure 1. Figure 1. Representation of the CO2 Cycle (https://serc.carleton.edu/eslabs/carbon/2a.html)

CO2 is a GHG not only produced by burning fuels and biomass. Humans exhale One Kilogram of it daily. Increase in population does not increase CO2, as exhaled balances out by inhaling. But when human population went up from 1 billion 200 years ago to 7 billion now, increase in human activity led to an imbalance in the atmosphere and the Oceans due to release of CO2 and Methane. Biomass generation too is dwindling due to the population pressure. Thus, this imbalance of accumulating matter capable of absorbing heat is the main reason for global warming.

Biosynthesis of Natural Rubber About 2000 plant species produce NR, but Hevea brasiliensis produce commercially exploitable dispersion in water as latex. The biological reason for NR production is not clear, but it may prevent pathogenic microorganisms entering the tree. Latex is found in horizontally arranged interconnected cells called laticifer, in the bark of the tree, High yielding plantations with about 400 trees per hectare have reported a production of 2500 Kg/NR /Year. The theoretical yield potential is estimated at, 7,000 to 10,000 kg/Ha/Year. A tree giving 15 to 30g of rubber per day, tapping on alternative days yields 2.2-4.5 Kg of NR per year. According to Apollo Vredestein R and D, on average 1.9 Kg of NR goes into a tire and a tree produces enough rubber to make 2 tires per year or 50 in lifetime.

Plants take in CO2 for survival. Some converts part into an edible form, as carbohydrate and fats while the rest is converted to forms like cellulose. These may end up as wood, becoming a Carbon sink for a length of time. In rubber trees, the process extends converting part of CO2 to a rubber hydrocarbon containing Carbon and Hydrogen, more akin to Petroleum. This wonder tree makes a hydrocarbon in few minutes, while nature took millions of years to convert biomass derived from CO2 to Petroleum.

The biosynthetic pathway for NR in Hevea begins with the monomer precursor, Isopentenyl pyrophosphate (IPP). IPP is an adduct of Pyrophosphoric acid and Isoprene monomer. However, IPP is not an uncommon material, limited to Hevea, but is formed from carbohydrates, in other plants, algae, bacteria, in mammals and humans. The formation of IPP is said to occur by following two pathways; Mevalonate (MVA) or non-mevalonate (non-MVA), deoxy-xylulose pathway. In rubber trees, breakdown products from carbohydrates like Pyruvates and Glyceraldehydes are transformed into IPP, in Cytosol in Cytoplasm/Plastids in plant cells, in several stages in the presence of many enzymes like mevalonate kinase (MVK) and mevalonate diphosphate decarboxylase (MVD). Figure 2.

Figure 2 Representation of the Formation of IPP through MVA and Non-MVA Pathways (Chiang. C. C. K, 2013, PhD Thesis, the Graduate Faculty of the University of Akron).

On isomerisation with enzyme, Isomerase IPP is converted to Dimethyl allyl pyrophosphate (DMPP). IPP and DMPP are building blocks for diverse groups of bio-molecules like Cholesterol, Vitamin K, Coenzyme Q10 (CoQ10) and Cis-polyisoprene (NR). Figure 3

Figure 3 Pathway to NR Biosynthesis

In rubber producing Russian dandelion (Taraxacum koksaghyz Rodin), enzyme transformation of sugars enrich NR formation. In the summer months, dandelions produce excess sugars and store it as Inulin. The possibility of metabolic engineering assisted enzyme degradation of Inulin to enhance production of IPP and then to NR has been explored for dandelion. Meanwhile Researchers have succeeded in decoding the Genome sequence in Hevea. This can lead to high yielding rubber clones, by locating genes responsible for biosynthesis of rubber.

Latex with 30% NR and 5% non-rubbers is produced in special cells called laticifers located horizontally and a lateral cut of the bark exposes most number, giving latex. Since the laticifer density is genotype dependant determining latex yield, it can give the direction for biologists as a selection marker for high yielding clones. In older rubber trees chemicals inducing Ethylene formation in the bark-tissue or generated it in situ like 2-Chloroethylphosphonic acid, are used as yield stimulants. Such developments, together with appropriate nutrition infusion, can increase NR yields, making rubber cultivation attractive to farmers.

Chloroethylphosphonic acid

Hevea brasiliensis is a dual-purpose tree, making Carbon sinks from CO2 in two ways, as a hydrocarbon and as wood, extracted in a 30-year cycle. Plants like wheat and rice also fix CO2 to give edible Carbohydrates, often twice a year. Nevertheless, human/animal consumption of edible carbohydrates quickly gives CO2 back to the environment. Thus with respect to environmental benefits, producing NR by growing rubber trees is a more favourable option. Fortunately, rubber cultivation has increased from 9.9 in 1975 to 14.0 million hectares in 2018 giving these benefits worldwide.

Preserving and enhancing rubber cultivation

The rubber farmer does a silent service by extracting latex and thus removing substantial quantity of GHG on a daily basis. As NR based products stay longer in service, Carbon in it remains intact for a longer period without burdening the environment. Each tree has the uncanny ability to function as a tap, working 150 days a year to clean up the environment unlike other plant-based options. It leaves a raw material as timber derived from GHG, extracted in every 30-year cycle giving 50 Kg of wood/tree. The global potential for wood at a replanting rate of 3% of acreage annually is, approx 7.30 Mn Tons/ year.

The environmental benefits can be maximised if the farmer taps the tree every other day for 11 months of the year if their livelihood is secularly safeguarded. Going into alternatives for from existing land is counterproductive to the environment. The negative process will occur only if the farmer finds the daily sustenance by growing rubber becomes a hard task. To encourage the farmer, requires a collective and a concerted effort from:

 Buyers giving stable/reasonable price

 Biologists developing fast growing, high yielding, drought and disease resistant trees

 Cultivation experts developing new and less-laborious extraction techniques and attractive intercropping practices

 Technologists adding value to existing NR products and developing new products

• Chemists by modification to give new elastomeric materials from NR as raw materials for other processes

• Environmentalists by increasing international awareness of the benefits of growing rubber

With respect to increased appreciation of the capability of modified NR forms, an enterprising tire manufacturer uses Epoxidised NR/Silica combination in automobile tire treads, to give higher wet grip and low rolling resistance tires. Such greener tires used in hybrid and electric cars, made these vehicles more environmental friendly. Olefinic elastomers like NR, contains reactive double bonds with potential to be modified as raw materials in many applications. Table 1, Figures 4 and 5. Such developments will give impetus to the sustainability and growth of an industry, benefitting the rubber farmer while fixing more GHG as well.

 

 

 

 

 

 

 

 

 

 

ENDS

References:

1. Bhowmik. I (2006), Tripura Rubber Mission Technical Bulletin 2. https://www.co2.earth/

3. Rao. P. S, et.al (1998), Agricultural and Forest Meteorology 3, 90

4. Chiang. C. C. K (2013), Natural rubber biosynthesis, PhD Thesis, The Graduate Faculty of The University of Akron, USA 5. Decoding the rubber tree genome, https://www.sciencedaily.com/releases/2016/06/160624100225.htm

 

 

Dr Sunil E Fernando is Former Executive Director, DPL Group, Sri Lanka, Managing Director Dipped Products (Thailand) Limited, Former Director, DPL Plantations and Kelani Valley Plantations Limited, Sri Lanka, and a Consultant - Latex Products

Black Swan Graphene Inc. (Black Swan) has formally stated that it has retained DS Market Solutions Inc. (DS Market) to offer market making services in compliance with TSXV standards, subject to the TSXV's approval.

With the aim of improving market depth and raising the liquidity of the company's common shares, DS Market will supply Black Swan with liquidity services in accordance with the terms of TSXV Policy 3.4. In addition to using its own funds to provide the services, DS Market has no direct or indirect stake in Black Swan's securities and no entitlement to purchase them, with the exception of assets required for liquidity. The services are offered by DS Market via Canaccord Direct DMA. DS Market has no direct or indirect stake in the firm or its securities, and Black Swan and DS Market are independent, unaffiliated, and unconnected businesses, reads the statement.

The statement further states that Black Swan will pay DS Market USD 5,000 per month from its available funds in exchange for the services for a minimum of one month, with the agreement being renewed for successive one-month durations. Thirty days before the end of the then-current term, either party may discontinue the agreement by giving writing notice to that effect. On 1 May 2025, DS Market will start offering its services.

The Rubber Board, which is observing its 77th anniversary this year, organised a press conference to showcase a novel method developed by the Rubber Research Institute of India (RRII) for recovering high-quality rubber from skim latex.

The new technique creates rubber lumps by treating the skim latex with a specific chemical mixture for 24 hours, then allowing the acid to coagulate. After that, these lumps may be dried and turned straight into skim crepe. About 3–4 percent of the rubber used to make Centrifuged Latex (Cenex) is skim latex, a by-product of the process. Cenex is frequently used in the production of goods including balloons, condoms, and gloves. About 10 percent of the natural rubber produced in India is converted into Cenex via centrifugation, which is accomplished at more than 40 centrifuging facilities.

The current method for recovering skim rubber is the acid coagulation of skim latex, which produces a slurry of skim rubber. After being packed into many plastic sacks, this slurry is allowed to solidify and dewater for two weeks. Skim crepe is made by further processing the resultant skim powder. But this traditional approach is labour-intensive, unrefined and results in bad odours, and it only generates rubber of poor grade. It has also caused public outcry and legal conflicts in the vicinity of Cenex enterprises, and it presents difficulties for wastewater treatment facilities. With the innovative method created by RRII, plastic bags are no longer used and processing takes only twenty-four hours. In addition to improving environmental sustainability and guaranteeing full recovery of premium rubber from skim latex, it drastically reduces offensive odours.

The Federation of Latex Processors (FLP), a group of owners of centrifuged latex factories, has been granted access to this technology on a fee basis. Other organizations and Cenex units can also purchase it. The product is marketed as Indian Purified Skim Rubber (IPSR) by the Rubber Board, which is also working on a patent for the concept. Rubber companies nationwide have expressed a strong interest in employing IPSR in product manufacture as it provides a competitive edge because of its improved quality and reduced cost.

Several efforts to solve various problems that exist in the rubber value chain were also addressed at the press conference. At the press conference, it was revealed that a nationwide celebration of the Silver Jubilee of the National Institute for Rubber Training (previously the Rubber Training Institute) would be organised, with participation from all relevant parties. M Vasanthagesan IRS (Executive Director, Rubber Board), Dr T Siju (Rubber Production Commissioner), Dr M D Jessy (Director-in-Charge, Rubber Research Institute of India) and representatives of the Federation of Latex Processors were in attendance.

Kraton Corporation, a leading global sustainable producer of speciality polymers and high-value bio-based products derived from pine wood pulping co-products, has expanded its CirKular+ product line with the launch of CirKular+ Paving Circularity Series C5000 in line with its long-term vision to create innovative solutions for a sustainable tomorrow.

The CirKular+ Paving Circularity Series addresses the changing demands of the paving industry to use more reclaimed asphalt and lower greenhouse gas (GHG) emissions. It allows for the addition of up to 50 percent or more reclaimed asphalt to the asphalt mix in surface layers while enhancing performance and processability. It increases the modified asphalt's resilience while maintaining resistance to permanent deformation and lowering the pavement's lifetime carbon footprint.  C5000 satisfies requirements for asphalt surface materials and is compatible with Warm Mix Asphalt technology.

Pedro Lopes, Kraton Global VP of Strategic Marketing, Product Management and Supply Chain, said, “Launching the Paving Circularity Series is a testament to our commitment to sustainability and innovation. In Europe, the paving industry is actively working to increase circularity and reduce GHG emissions in alignment with the European Green Deal and the EU’s 2050 climate neutrality goals. The new series helps unlock value-added circularity by enabling polymer-modified bitumen (PMB) producers and contractors to increase the reuse of reclaimed asphalt, thereby reintegrating it back into the road surface layer.”

Perth-based CTS Tyre Recycling is forging ahead with its plans to reshape the options for disposal of end-of-life tyres in Western Australia.

The company, a part of the wider Cometti Group, a family-owned business with more than 40 years of experience in the tyre industry, has invested more than USD 40 million in a state-of-the-art recycling plant at Neerabup, north of Perth, that processes waste tyres into crumb rubber, tyre derived products, reusable high tensile steel wire and reusable textile. The company also made some additions to its management ranks and expanded its links with industry associations as it moves forward with its strategy. These tyres, along with all other sizes, will be remanufactured in the new Neerabup factory into new, high-value goods like load-restraining matting, gym matting, equestrian and farm matting and acoustic underlay.

Leigh Cometti, the company’s Managing Director, identified a potential to diversify into the recycling of end-of-life tyres, concentrating on some of the huge off-the-road tyres utilised in the mining services and agricultural industries. Over 90 percent of the bigger OTR tyres now in use in Western Australia are thought to end up in landfills. Tyres are commonly buried in pits left behind during excavation, which results in the greatest landfill disposals in the Pilbara area. The recycling programmes will lessen the need for more virgin products in addition to decreasing landfill discharge.

Cometti has brought on two seasoned senior level managers to support him as the company grows. Joseph Jeevaraj has joined as Chief Financial Officer, while Darren Rodwell has been named Chief Operating Officer. Both positions work for the Cometti Group, which also owns the Bunbury Trucks Sales and Service dealership, CTS People and Mechanics Recruitment.