DIFFERENT WAXES IN RUBBER INDUSTRY

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  • June 26, 2020
DIFFERENT WAXES IN RUBBER INDUSTRY
  • Plastic ( soft or malleable) at normal ambient temperatures
  • A melting point above approximately 45 °C.
  • A  relatively low viscosity when melted (unlike many plastics)
  • Insoluble in water
  • Hydrophobic
Fig No 1

We shall be discussing here on the waxes which are only being used in the rubber and plastic industry. Beeswax, perhaps , is the first wax which used by human in the beginning of our civilization, was one of the important renewable source of fuel. The honey comb formed by bees has typical hexagonal geometric pattern (Fig.1). Bees wax is used in tire building drum, if the rubber is too sticky, it can also be used in two roll mill to take care of rubber sticking to the rolls. It is frequently being used in the BC, MC, PC, TB  inner-tube making industry during pre-forming operation in the green stage when inner-tubes are expanded under mild air pressure just before curing in mold.

 

The main commercial source of wax is, however, crude oil but not all crude oil refiners produce wax. "Mineral" wax can also be produced from lignite. Plants, animals and even insects produce materials sold in commerce as "wax". There are five categories of waxes being used in rubber industries :

  • Bees Wax
  • Paraffin Wax - made of long-chain alkane hydrocarbons
  • Microcrystalline Wax - with very fine crystalline structure
  • Chlorinated Paraffin Wax
  • Polyethylene Wax
  • Chlorinated Polyethylene Wax

The major uses of petroleum based waxes are in rubber, cosmetics and in Candle industry. They are generally white in color but show usual brown color (Fig.2) due to contaminated with oil traces. Two types of waxes, in general, are used in rubber industry, Paraffinic wax and Microcrystalline wax. Its normal dose is 1-3 phr and high level of wax impairs low temperature flexibility and compression set. Rubber compounder considers wax as a very important processing aid because it has following advantages:

 

  • Improves mixing properties
    Fig No 2
    Petroleum Based Wax

     

  • Improves dispersion of filler and other ingredients
  • Improves extrusion properties
  • Improves upon extrudate and calendared surface finish
  • Protects surface and acts as antioxidant /antiozonate

 

 

Paraffin and Microcrystalline waxes are derived from petroleum. They are easy to recover and offer a wide range of physical properties that can often be tailored by refining processes. Most producers offer two distinct types of petroleum waxes: paraffins, which are distinguished by large, well formed crystals; and microcrystallines, which are higher melting waxes with small, irregular crystals. Microcrystalline wax contains substantial proportions of branched and cyclic saturated hydrocarbons in addition to normal alkanes.

Some producers also sell "intermediate" wax, in which the boiling range is cut where the transition in crystal size and structure occur. Petroleum wax producers also characterize wax by degree of refinement; fully refined paraffin has oil content generally less than 0.5% and fully-refined micro-crystalline less than 3%. Paraffin wax produced from petroleum is essentially a pure mixture of normal and iso-alkanes without the esters, acids, etc. found in the animal and vegetable-based waxes.

Paraffin wax (or simply "paraffin") is mostly found as a white, odorless, tasteless, waxy solid, with a typical melting point between about 47-64 °C  and having a density of around 0.9 g/cm3. It is insoluble in water, but soluble in ether, benzene, and certain esters. Paraffin is unaffected by most common chemical reagents, but burns readily. Paraffin wax is generally unbranched hydrocarbon having carbon above C17 and  are solid at room temperature. Their carbon atoms typically ranges between C17 - C30 and having typical melting point around 60°C. All paraffinic wax are recovered from fractional distillation of petroleum.The name paraffin implies that it contains straight hydrocarbon structure but it has branch also. Branched paraffins are called ‘Isoparafins’ and cyclic parafins are called ‘Cresines’ or ‘Isoceresies’.

Fig.3: Paraffinic  Wax
Fig.4: Micro Crystalline Wax

 

 

 

 

 

 

Pure paraffin wax dose in rubber compounding varies from 1-3 phr. Pure paraffin wax is rarely used these days in rubber industry as it has oozing character and in excess it causes blooming on green rubber components, that results in reduction in compound tack. They are frequently blended with microcrystalline wax in rubber compounding therefore.

Pure paraffin wax is an excellent electrical insulator, with an electrical resistivity of between 1013 and 1017 ohm meter. This is better than nearly all other materials except some plastics (notably teflon or polytetrafluoroethylene). It is an effective neutron moderator and was used in James Chadwick's 1932 experiments to identify the neutron. Paraffin wax (C25H52) is an excellent material to store heat, having a specific heat capacity of 2.14–2.9 J g–1 K–1 (joule per gram per kelvin) and a heat of fusion of 200–220 J g–1(joule per gram). This property is exploited in modified drywall for home building material.

Microcrystalline waxes: This is produced by de-oiling petrolatum, as part of the petroleum refining process. Microcrystalline wax contains a higher percentage of isoparaffinic (branched) hydrocarbons and naphthenic hydrocarbons. It is characterized by the fineness of its crystals in contrast to the larger crystal of paraffin wax. It consists of high molecular weight saturated aliphatic hydrocarbons with comparatively higher melting point than paraffinic wax. It is generally darker, more viscous, denser, tackier and more elastic than paraffin waxes. The elastic and adhesive characteristics of microcrystalline waxes are related to the non-straight chain components which they contain. Typical microcrystalline wax crystal structure is small and thin, making them more flexible than paraffin wax. It is commonly used in rubber formulation and cosmetic formulations.

Its usual carbon atom ranges from C40–C70 , having comparatively higher melting point (Fig.4) between 80-105 0C because they have higher number of carbon. Common dose in rubber compounding is between 1-3 phr. Some time higher dose of  100% Micro crystalline wax is difficult to process and as a result they are often blended with paraffinic wax for rubber use. Blending is also done for economical reasons as microcrystalline wax is comparatively costlier. Paraffinic wax, having smaller molecular weight bleeds faster in cured rubber article, whereas, 100% micro crystalline wax  will have inherent resistance to faster volatilization and eventually, blended wax will have an intermediate property. Refineries may also utilize blending facilities to combine paraffin and microcrystalline waxes. This type of activity is prevalent especially for industries such as tire and rubber industries.

Higher dose of antioxidant and anti ozonates are always advised to add along with microcrystalline wax because the later help slower migration of antioxidant and antiozonates on the product surface and thereby increase on the product durability against ageing process. Tire curing bladder is often blended with 1-3 phr of microcrystalline wax.

Fig.5: Polyethylene, Fig.6: Polyethylene wax
Fig.7: Chlorinated Polyethylene waxes (CPE)

Chlorinated Paraffin Wax

Upon chlorination of paraffinic wax we get Chlorinated Paraffin Wax(CPW). This is available in batch process that is processed from effective exothermic reaction. This reaction generates a by-product hydrochloric acid that is later removed out of the solution. Finally stabilizer and solution is mixed that provide the required final product, which is used in various industrial applications. With 30 to 70% chlorine and insolubility in water, these CPWs have low vapor pressure. Chlorinated Paraffin Wax is highly inert, insoluble in water and they have low vapor pressure. Generally used as plasticizers in plastic and elastomers, where flame retardant property is important.

Polyethylene waxes (PE-Wax)

Polyethylene waxes or PE-Wax is same familiar polyethylene chemical structure (Fig.5) but with lower molecular weight , generally around or less than 3000.This is a processing aid in elastomer and plastics but basically they are a form of synthetic resins. It is a white solid product (Fig.6) appears in the market as powdery, lumpy, or flaky product. It is a non-toxic product having concentrated distribution of molecular weight of 1500 with specific gravity about 0.94 with high softening point but low fusion viscosity with melting point; 112 - 118°C, melt peak 110 °C, flash point 210°C, minimum. It has excellent stability against polishing, scratch resistance, metal mark resistance, scuff resistance. PE-Wax is resistant to water and chemical materials.

 

WACKER Exhibits Silicone-Based Innovations At JEC World 2026

WACKER Exhibits Silicone-Based Innovations At JEC World 2026

The Wacker Group is showcasing two new silicone-based impact modifiers, GENIOPERL W37 and GENIOPERL W38, at the JEC World composites exhibition. These additives are engineered to enhance the mechanical properties of thermosetting resins such as epoxies and vinyl esters. Their specialised molecular structure, built on functional silicone, facilitates a distinct phase separation within the resin matrix. This process creates tiny elastomeric domains that increase toughness and help prevent composite materials from fracturing under stress. Sustainability was a key consideration in their design, leading to a notably reduced cyclics content. Both modifiers disperse readily with simple mixing equipment, maintain their effectiveness even at low concentrations and do not compromise the material’s inherent strength, viscosity or thermal resistance. The company is located at booth 5N142 at JEC World, taking place in Paris from 10 to 12 March 2026.

GENIOPERL W37 is specifically formulated to boost impact resistance in low-temperature environments. It is recommended for use at concentrations between two and eight percent by weight, a level at which it has minimal impact on the resin’s viscosity or the cured product’s glass transition temperature. Achieving optimal dispersion requires processing temperatures of at least 50 degrees Celsius. Similarly, GENIOPERL W38 also improves impact strength at very low temperatures when used within the same dosage range. It offers the added benefit of containing anti-foaming agents, making it particularly suitable for casting processes conducted under reduced pressure.

A third major highlight at the Wacker booth will be POWERSIL Resin 710, a silicone compound developed for components that must endure extreme heat. This material can be processed using compression moulding, pressure gelation or injection moulding. Parts manufactured from it meet the criteria for thermal class R, signifying their ability to withstand prolonged exposure to temperatures reaching 220 degrees Celsius. As an alternative to high-performance polymers like PTFE and PEEK, POWERSIL Resin 710 provides excellent electrical insulation, mechanical strength and UV stability. It is solvent-free, has a low viscosity for easier processing and is available in both peroxide-curing and catalyst-curing versions.

Wacker’s exhibition will also feature a range of other specialised products for the composites industry. These include SILRES silicone resins for enhancing electrical insulation and flame retardancy, HDK pyrogenic silica for precise rheology control, VINNAPAS low-profile additives to reduce shrinkage and GENIOSIL organofunctional silanes for promoting adhesion and treating fillers and fibres.

Sri Trang Agro-Industry Announces Net Zero Commitment Under SBTi (Phase3)

Sri Trang Agro-Industry Announces Net Zero Commitment Under SBTi (Phase3)

Sri Trang Agro-Industry Public Company Limited (STA) has formally committed to the Science Based Target Initiative for Industrial Greenhouse Gas Reduction towards Net Zero (Phase 3), organised by Thailand Greenhouse Gas Management Organization (TGO) in collaboration with the Center of Excellence in Eco-Energy, Faculty of Engineering, Thammasat University. This declaration positions the company among 16 leading Thai organisations committed to embedding scientifically validated climate targets throughout their operations and supply networks.

STA has established a target to cut Scope 1 and 2 emissions by 23 percent by 2030, using 2024 as its reference point, with the ultimate ambition of reaching net zero by 2050. These goals directly support the international objective of capping global warming at 1.5 degrees Celsius. Beyond direct emissions, the company is enhancing its rubber and teak plantations to function as carbon sinks, generating certified credits while supplying raw materials. This strategy aligns with its net zero pathway and responds to the European Union’s Corporate Sustainability Due Diligence Directive, which promotes heightened corporate environmental accountability.

By embracing this initiative, STA underscores its vision of evolving into a low-carbon, fully integrated natural rubber enterprise. The company aims to reconcile commercial growth with ecological and social stewardship, thereby aiding Thailand’s wider shift towards a sustainable, low-carbon future.

Solvay Joins Forces With Belgian Rugby Federation As Official Partner

Solvay Joins Forces With Belgian Rugby Federation As Official Partner

Solvay has entered into an official partnership with the Belgian Rugby Federation, marking the beginning of a collaboration founded on mutual principles and a unified goal: uniting communities and fostering human development. This alliance naturally extends from the company's enduring philosophy, established over 160 years ago by its founder Ernest Solvay. His humanistic ideals, emphasising education, inclusivity and communal strength as the foundations of progress, continue to drive the organisation's sustainability framework and its commitment to making a worldwide positive impact.

The sport of rugby embodies these same values through its inherent focus on trust, collective effort and perseverance. These attributes empower individuals while simultaneously forging a stronger, unified entity. Through this new role, Solvay will provide backing to the men's national teams, including the Rugby 7s side, the under-20 squads and the refereeing community. This support is designed to enhance accessibility and growth opportunities within the sport for young athletes and local clubs.

Beyond the field, this initiative will allow international Solvay teams to unite around key matches, reinforcing bonds with local stakeholders and cultivating a collective sense of mission. This partnership reinforces a conviction held since the company's inception: that human advancement is a shared endeavour, gaining true strength and momentum when people come together.

Philippe Kehren, CEO, Solvay, said, “Rugby expresses a belief that Solvay holds deeply: people go further when they move forward together, the only ‘en avant’ that is allowed. This partnership celebrates Solvay’s heritage while opening new possibilities for connection – bringing colleagues and communities together around the world, especially when the national team competes abroad.”

Michiel Leysen, President, Belgian Rugby Federation, said, “The Belgian Rugby Federation is honoured to welcome Solvay as its official partner. This partnership will help expand the reach of rugby and inspire new generations of players.”

ARLANXEO Achieves ISCC PLUS Certification At Texas Site For Therban (HNBR) And Buna (BR)

ARLANXEO Achieves ISCC PLUS Certification At Texas Site For Therban (HNBR) And Buna (BR)

ARLANXEO has announced that its Therban (HNBR) and Buna (BR) production facilities in Orange, Texas, have been awarded ISCC PLUS certification. This recognition allows the site to manufacture and offer products bearing the ARLANXEO Eco label, which represents the company's range of certified sustainable elastomers developed through a mass balance approach. As a result, ARLANXEO can now provide customers across North America and other global markets with verified sustainable alternatives that support carbon footprint reduction while preserving the high performance and reliability characteristic of Therban and Buna materials.

This achievement holds particular importance for the company's Specialty Elastomers division, as the Orange facility becomes the first Therban HNBR production site to earn this certification. It marks a significant step in broadening ARLANXEO's portfolio of sustainable high-performance elastomers. Additionally, the certification of Buna BR production at the same location further enriches the company's sustainable offerings, especially for clients in North America.

The ISCC PLUS certification is a globally acknowledged standard ensuring traceability, transparency and responsible sourcing throughout supply chains. By utilising the mass balance method to incorporate circular and renewable raw materials, ARLANXEO delivers Eco grades that enable customers to lower their environmental impact without sacrificing technical quality. This milestone aligns with the company's wider global sustainability strategy and represents continued progress in expanding its Eco portfolio across various sites and product lines, aiding customers in their shift towards more sustainable elastomer solutions.

Edwin Grootendorst, Global Head of Business Specialty Elastomers, said, “The Orange site is the first Therban HNBR production facility to receive ISCC PLUS certification and further strengthens the sustainability mission of ARLANXEO, as well as the Eco portfolio of the Specialty Elastomers cluster.”

Rohit Prabhune, Global Head of Business Basic Elastomers, said, “With Orange joining our existing ISCC PLUS-certified Buna sites, ARLANXEO now has ISCC+ Certified Basic Elastomers producing sites on three continents, with a truly global reach. This reinforces our commitment to providing customers with circular, mass balanced solutions that help reduce environmental impact while maintaining the performance they expect.”

Jay Capelli, Regional Head of Sales NORAM, said, “This certification helps solidify ARLANXEO’s position in the NORAM region as a premium supplier and partner – and supports the sustainability ambitions of our customers across key industries.”