DIFFERENT WAXES IN RUBBER INDUSTRY

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  • June 26, 2020
DIFFERENT WAXES IN RUBBER INDUSTRY
  • Plastic ( soft or malleable) at normal ambient temperatures
  • A melting point above approximately 45 °C.
  • A  relatively low viscosity when melted (unlike many plastics)
  • Insoluble in water
  • Hydrophobic
Fig No 1

We shall be discussing here on the waxes which are only being used in the rubber and plastic industry. Beeswax, perhaps , is the first wax which used by human in the beginning of our civilization, was one of the important renewable source of fuel. The honey comb formed by bees has typical hexagonal geometric pattern (Fig.1). Bees wax is used in tire building drum, if the rubber is too sticky, it can also be used in two roll mill to take care of rubber sticking to the rolls. It is frequently being used in the BC, MC, PC, TB  inner-tube making industry during pre-forming operation in the green stage when inner-tubes are expanded under mild air pressure just before curing in mold.

 

The main commercial source of wax is, however, crude oil but not all crude oil refiners produce wax. "Mineral" wax can also be produced from lignite. Plants, animals and even insects produce materials sold in commerce as "wax". There are five categories of waxes being used in rubber industries :

  • Bees Wax
  • Paraffin Wax - made of long-chain alkane hydrocarbons
  • Microcrystalline Wax - with very fine crystalline structure
  • Chlorinated Paraffin Wax
  • Polyethylene Wax
  • Chlorinated Polyethylene Wax

The major uses of petroleum based waxes are in rubber, cosmetics and in Candle industry. They are generally white in color but show usual brown color (Fig.2) due to contaminated with oil traces. Two types of waxes, in general, are used in rubber industry, Paraffinic wax and Microcrystalline wax. Its normal dose is 1-3 phr and high level of wax impairs low temperature flexibility and compression set. Rubber compounder considers wax as a very important processing aid because it has following advantages:

 

  • Improves mixing properties
    Fig No 2
    Petroleum Based Wax

     

  • Improves dispersion of filler and other ingredients
  • Improves extrusion properties
  • Improves upon extrudate and calendared surface finish
  • Protects surface and acts as antioxidant /antiozonate

 

 

Paraffin and Microcrystalline waxes are derived from petroleum. They are easy to recover and offer a wide range of physical properties that can often be tailored by refining processes. Most producers offer two distinct types of petroleum waxes: paraffins, which are distinguished by large, well formed crystals; and microcrystallines, which are higher melting waxes with small, irregular crystals. Microcrystalline wax contains substantial proportions of branched and cyclic saturated hydrocarbons in addition to normal alkanes.

Some producers also sell "intermediate" wax, in which the boiling range is cut where the transition in crystal size and structure occur. Petroleum wax producers also characterize wax by degree of refinement; fully refined paraffin has oil content generally less than 0.5% and fully-refined micro-crystalline less than 3%. Paraffin wax produced from petroleum is essentially a pure mixture of normal and iso-alkanes without the esters, acids, etc. found in the animal and vegetable-based waxes.

Paraffin wax (or simply "paraffin") is mostly found as a white, odorless, tasteless, waxy solid, with a typical melting point between about 47-64 °C  and having a density of around 0.9 g/cm3. It is insoluble in water, but soluble in ether, benzene, and certain esters. Paraffin is unaffected by most common chemical reagents, but burns readily. Paraffin wax is generally unbranched hydrocarbon having carbon above C17 and  are solid at room temperature. Their carbon atoms typically ranges between C17 - C30 and having typical melting point around 60°C. All paraffinic wax are recovered from fractional distillation of petroleum.The name paraffin implies that it contains straight hydrocarbon structure but it has branch also. Branched paraffins are called ‘Isoparafins’ and cyclic parafins are called ‘Cresines’ or ‘Isoceresies’.

Fig.3: Paraffinic  Wax
Fig.4: Micro Crystalline Wax

 

 

 

 

 

 

Pure paraffin wax dose in rubber compounding varies from 1-3 phr. Pure paraffin wax is rarely used these days in rubber industry as it has oozing character and in excess it causes blooming on green rubber components, that results in reduction in compound tack. They are frequently blended with microcrystalline wax in rubber compounding therefore.

Pure paraffin wax is an excellent electrical insulator, with an electrical resistivity of between 1013 and 1017 ohm meter. This is better than nearly all other materials except some plastics (notably teflon or polytetrafluoroethylene). It is an effective neutron moderator and was used in James Chadwick's 1932 experiments to identify the neutron. Paraffin wax (C25H52) is an excellent material to store heat, having a specific heat capacity of 2.14–2.9 J g–1 K–1 (joule per gram per kelvin) and a heat of fusion of 200–220 J g–1(joule per gram). This property is exploited in modified drywall for home building material.

Microcrystalline waxes: This is produced by de-oiling petrolatum, as part of the petroleum refining process. Microcrystalline wax contains a higher percentage of isoparaffinic (branched) hydrocarbons and naphthenic hydrocarbons. It is characterized by the fineness of its crystals in contrast to the larger crystal of paraffin wax. It consists of high molecular weight saturated aliphatic hydrocarbons with comparatively higher melting point than paraffinic wax. It is generally darker, more viscous, denser, tackier and more elastic than paraffin waxes. The elastic and adhesive characteristics of microcrystalline waxes are related to the non-straight chain components which they contain. Typical microcrystalline wax crystal structure is small and thin, making them more flexible than paraffin wax. It is commonly used in rubber formulation and cosmetic formulations.

Its usual carbon atom ranges from C40–C70 , having comparatively higher melting point (Fig.4) between 80-105 0C because they have higher number of carbon. Common dose in rubber compounding is between 1-3 phr. Some time higher dose of  100% Micro crystalline wax is difficult to process and as a result they are often blended with paraffinic wax for rubber use. Blending is also done for economical reasons as microcrystalline wax is comparatively costlier. Paraffinic wax, having smaller molecular weight bleeds faster in cured rubber article, whereas, 100% micro crystalline wax  will have inherent resistance to faster volatilization and eventually, blended wax will have an intermediate property. Refineries may also utilize blending facilities to combine paraffin and microcrystalline waxes. This type of activity is prevalent especially for industries such as tire and rubber industries.

Higher dose of antioxidant and anti ozonates are always advised to add along with microcrystalline wax because the later help slower migration of antioxidant and antiozonates on the product surface and thereby increase on the product durability against ageing process. Tire curing bladder is often blended with 1-3 phr of microcrystalline wax.

Fig.5: Polyethylene, Fig.6: Polyethylene wax
Fig.7: Chlorinated Polyethylene waxes (CPE)

Chlorinated Paraffin Wax

Upon chlorination of paraffinic wax we get Chlorinated Paraffin Wax(CPW). This is available in batch process that is processed from effective exothermic reaction. This reaction generates a by-product hydrochloric acid that is later removed out of the solution. Finally stabilizer and solution is mixed that provide the required final product, which is used in various industrial applications. With 30 to 70% chlorine and insolubility in water, these CPWs have low vapor pressure. Chlorinated Paraffin Wax is highly inert, insoluble in water and they have low vapor pressure. Generally used as plasticizers in plastic and elastomers, where flame retardant property is important.

Polyethylene waxes (PE-Wax)

Polyethylene waxes or PE-Wax is same familiar polyethylene chemical structure (Fig.5) but with lower molecular weight , generally around or less than 3000.This is a processing aid in elastomer and plastics but basically they are a form of synthetic resins. It is a white solid product (Fig.6) appears in the market as powdery, lumpy, or flaky product. It is a non-toxic product having concentrated distribution of molecular weight of 1500 with specific gravity about 0.94 with high softening point but low fusion viscosity with melting point; 112 - 118°C, melt peak 110 °C, flash point 210°C, minimum. It has excellent stability against polishing, scratch resistance, metal mark resistance, scuff resistance. PE-Wax is resistant to water and chemical materials.

 

Birla Carbon Spain Secures EUR 2 Million SODERCAN Grant For Steam Turbine Project In Cantabria

Birla Carbon Spain Secures EUR 2 Million SODERCAN Grant For Steam Turbine Project In Cantabria

Birla Carbon Spain has been awarded a EUR 2 million grant by the Society for Regional Development of Cantabria S.A. (SODERCAN), a public entity of the Government of Cantabria, to advance an energy autonomy initiative at its Cantabria plant. The funding announcement was made in late February during a visit attended by María José Sáenz de Buruaga, President of Cantabria; Eduardo Arasti, Minister of Industry, Employment, Innovation, and Trade of Cantabria and Ángel Pedraja, CEO of SODERCAN. The grant forms part of a broader investment project by Birla Carbon Spain aimed at strengthening energy self-sufficiency at the facility.

The funding will support the installation of a 4 MW back-pressure steam turbine at the Cantabria unit, enabling it to generate electricity and steam internally for operations. When completed, the project is expected to reduce CO2 emissions annually while also decreasing reliance on water from the Miera River for cooling purposes and reducing process water discharge. Beyond these environmental benefits, the investment will help safeguard nearly 200 direct and indirect jobs associated with the facility, reinforcing the company's commitment to both sustainability and regional economic stability.

During the visit, President María José Sáenz de Buruaga was briefed on the technical and environmental aspects of the project and described it as a collective success. She recognised Birla Carbon Spain's strategic role in the regional industrial ecosystem and its position as a benchmark for innovation in Europe. The initiative represents a significant step towards sustainable manufacturing practices while demonstrating the company's dedication to long-term operational viability and environmental stewardship in Cantabria.

Dale Clark, Chief Manufacturing Officer, Americas & EMEA, Birla Carbon, said, “We were honoured to welcome the President of Cantabria, the Minister of Employment, Innovation and Trade of Cantabria and the CEO of SODERCAN to our Cantabria plant. Their support reflects the strategic importance of our operations to the region and the industries we serve with our carbon black solutions. The steam turbine will be key in helping the plant achieve energy autonomy, reducing our carbon footprint and strengthening long-term operational resilience. At Birla Carbon, we also remain continuously focused on improving energy efficiency, reducing water consumption and advancing sustainable manufacturing practices across our global operations.”

María José Sáenz de Buruaga, President of Cantabria, said, “With this contribution, not only does Birla Carbon win, but Cantabria wins too, because we are making decisive progress in the transformation of our production model and in our commitment to industrialisation.”

Flexsys Wins International Innovation Award For Breakthrough 6PPD Alternative

Flexsys, a global leader in advanced tyre additives and material-science solutions, has been honoured with the Chemical and Compounding Innovation of the Year Award at the Tire Technology International Awards for Innovation and Excellence. This recognition celebrates the company’s progress in creating a novel alternative to 6PPD for tyre manufacturing.

Driven by a significant challenge within the tyre industry, Flexsys’s dedicated research and development team, alongside respected federal and independent laboratories, pursued the creation of a next-generation replacement for 6PPD. Their investigation spanned hundreds of molecules from various chemical families, ultimately identifying several promising candidates that satisfy the stringent criteria for both tyre efficacy and environmental safety. Extensive laboratory testing, conducted both internally and by external parties, has confirmed that one of these candidates delivers robust antidegradant qualities while presenting a favourable toxicological profile. Significantly, this effective molecule is not a PPD chemical. Currently, performance trials are in progress with selected industrial collaborators, with further information regarding the specific molecule anticipated later this year.

The award itself is determined by a completely autonomous international jury composed of journalists and industry specialists. It is coordinated by Tire Technology International magazine, a publication owned by UKi Media & Events, which also organises the renowned Tire Technology Expo.

Neil Smith, Chief Technology and Sustainability Officer, said, “We are honoured to receive this industry recognition for our work, which reflects our commitment to delivering solutions that meet demanding performance requirements while advancing environmental responsibility. I’m incredibly proud of the Flexsys R&D team whose dedication and scientific rigor has allowed us to achieve this recognition. We believe collaboration across the tyre and materials ecosystem is essential to developing durable, scalable solutions for the industry and look forward to continuing this journey together.”

Matt Ross, Editor-In-Chief, Tire Technology International magazine, said, “The Tire Technology International Awards for Innovation and Excellence are recognised as the industry’s top accolades and aim to celebrate the best new technologies and innovations from all over the world. On behalf of all of the judges, we extend our congratulation to the Flexsys team on this win and their work to find a replacement for 6PPD in tyres.”

Pyrum Rebrands Recycled Materials To Strengthen Market Identity

Pyrum Rebrands Recycled Materials To Strengthen Market Identity

Pyrum Innovations AG has announced an immediate update to the nomenclature of its recycled material outputs as part of a strategic effort to reinforce its brand identity and underscore the distinctiveness of its offerings. The company’s thermolysis oil, formerly referred to as recycled oil, will now be designated TTO (ThermoTireOil). Similarly, what was previously known as recovered Carbon Black (rCB) will adopt the new name TTB (ThermoTireBlack).

This decision stems from inconsistencies observed across the broader market for recycled commodities. Materials sold under generic labels such as rCB or pyrolysis oil often vary significantly in composition, largely because they may contain residual additives or lack standardisation. In the case of rCB, for instance, the presence of inorganic elements from tyres can lead to blends that are unsuitable for certain high-performance applications. Pyrum’s output, by contrast, is produced through its patented thermolysis technology, which yields materials with a consistent and well-defined makeup. The new names are intended to reflect this precision and set them apart from less uniform alternatives.

The underlying production process remains centred on breaking down end-of-life tyres into their constituent elements. TTB has already entered series manufacturing in the tyre industry and is gaining recognition for use in products such as conveyor belts, seals, and protective coatings. TTO, meanwhile, functions as a renewable input for polymers used in clothing, automotive components and food-safe packaging.

Rollout of the new terminology begins at once and will be phased into all technical records, official certifications and customer communications. Although the labelling is new, the formulations and quality levels of the products themselves are unchanged.

Pascal Klein, CEO, Pyrum Innovations AG, said, “Our products are the result of years of development and intensive research. With the new designations TTO and TTB for our oil and our rCB, we make it clear that these are unique materials obtained from our unique thermolysis process.”

KRAIBURG TPE Secures EcoVadis Gold For Second Consecutive Year

KRAIBURG TPE Secures EcoVadis Gold For Second Consecutive Year

KRAIBURG TPE has earned gold medal from EcoVadis for the second consecutive year. This recognition reflects the performance of the company’s entire global operations, which collectively achieved this distinguished honour. The company posted new peak scores across all four evaluation categories, which include environmental impact, labour and human rights, ethical conduct and sustainable sourcing. Ranking in the 98th percentile, KRAIBURG TPE now stands among the top two percent of all companies rated by EcoVadis globally, reinforcing its status as a frontrunner in responsible corporate practices.

Within the plastics sector, sustainability has evolved into a fundamental driver of success. Growing public attention now extends beyond isolated topics, calling instead for businesses to offer clear and reliable sustainability reporting. Measurable indicators that track advancements and allow for objective comparisons across industry peers have thus become indispensable.

Having evaluated over 150,000 businesses, EcoVadis has cemented its role as one of the most trusted frameworks for assessing corporate sustainability. The benchmarks applied by the Paris-based organization across its categories are both rigorous and comprehensive. Given this demanding standard, KRAIBURG TPE’s 2022 achievement of a silver award in its debut year was particularly meaningful.

In 2025, the company reached a new milestone by receiving its first gold medal covering all global facilities, a testament to inter-site collaboration and the dedication of its entire workforce. This distinction was reaffirmed during the scheduled reassessment in January 2026, accompanied by even higher marks in every category. Such ongoing improvement demonstrates the company’s steadfast commitment to advancing its sustainability objectives consistently across international operations.

Oliver Zintner, CEO, KRAIBURG TPE, said, “For us, this second Gold Award is confirmation in many respects of the extraordinary achievements we have made in the field of sustainability in the past years. On the one hand, it demonstrates how strong our position is in international comparison. But above all, the award emphasises how continuously and persistently we pursue our sustainability goals in all categories. Results like that are not at all a matter of course in our competitive environment. They only become possible because our colleagues at all sites worldwide are closely working together in a partnership-based manner.”

Michael Pollmann, Sales & Marketing Director EMEA, said, “In addition to product quality, price and delivery reliability, sustainability criteria are a more and more important factor for our customers’ purchase decisions. The EcoVadis award represents the consistency and transparency with which we implement our sustainability promises. It is a relevant strategic competitive factor and is gaining in importance, particularly in view of increasing legal requirements in fields such as supply chain assessment.”