DIFFERENT WAXES IN RUBBER INDUSTRY

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  • June 26, 2020
DIFFERENT WAXES IN RUBBER INDUSTRY
  • Plastic ( soft or malleable) at normal ambient temperatures
  • A melting point above approximately 45 °C.
  • A  relatively low viscosity when melted (unlike many plastics)
  • Insoluble in water
  • Hydrophobic
Fig No 1

We shall be discussing here on the waxes which are only being used in the rubber and plastic industry. Beeswax, perhaps , is the first wax which used by human in the beginning of our civilization, was one of the important renewable source of fuel. The honey comb formed by bees has typical hexagonal geometric pattern (Fig.1). Bees wax is used in tire building drum, if the rubber is too sticky, it can also be used in two roll mill to take care of rubber sticking to the rolls. It is frequently being used in the BC, MC, PC, TB  inner-tube making industry during pre-forming operation in the green stage when inner-tubes are expanded under mild air pressure just before curing in mold.

 

The main commercial source of wax is, however, crude oil but not all crude oil refiners produce wax. "Mineral" wax can also be produced from lignite. Plants, animals and even insects produce materials sold in commerce as "wax". There are five categories of waxes being used in rubber industries :

  • Bees Wax
  • Paraffin Wax - made of long-chain alkane hydrocarbons
  • Microcrystalline Wax - with very fine crystalline structure
  • Chlorinated Paraffin Wax
  • Polyethylene Wax
  • Chlorinated Polyethylene Wax

The major uses of petroleum based waxes are in rubber, cosmetics and in Candle industry. They are generally white in color but show usual brown color (Fig.2) due to contaminated with oil traces. Two types of waxes, in general, are used in rubber industry, Paraffinic wax and Microcrystalline wax. Its normal dose is 1-3 phr and high level of wax impairs low temperature flexibility and compression set. Rubber compounder considers wax as a very important processing aid because it has following advantages:

 

  • Improves mixing properties
    Fig No 2
    Petroleum Based Wax

     

  • Improves dispersion of filler and other ingredients
  • Improves extrusion properties
  • Improves upon extrudate and calendared surface finish
  • Protects surface and acts as antioxidant /antiozonate

 

 

Paraffin and Microcrystalline waxes are derived from petroleum. They are easy to recover and offer a wide range of physical properties that can often be tailored by refining processes. Most producers offer two distinct types of petroleum waxes: paraffins, which are distinguished by large, well formed crystals; and microcrystallines, which are higher melting waxes with small, irregular crystals. Microcrystalline wax contains substantial proportions of branched and cyclic saturated hydrocarbons in addition to normal alkanes.

Some producers also sell "intermediate" wax, in which the boiling range is cut where the transition in crystal size and structure occur. Petroleum wax producers also characterize wax by degree of refinement; fully refined paraffin has oil content generally less than 0.5% and fully-refined micro-crystalline less than 3%. Paraffin wax produced from petroleum is essentially a pure mixture of normal and iso-alkanes without the esters, acids, etc. found in the animal and vegetable-based waxes.

Paraffin wax (or simply "paraffin") is mostly found as a white, odorless, tasteless, waxy solid, with a typical melting point between about 47-64 °C  and having a density of around 0.9 g/cm3. It is insoluble in water, but soluble in ether, benzene, and certain esters. Paraffin is unaffected by most common chemical reagents, but burns readily. Paraffin wax is generally unbranched hydrocarbon having carbon above C17 and  are solid at room temperature. Their carbon atoms typically ranges between C17 - C30 and having typical melting point around 60°C. All paraffinic wax are recovered from fractional distillation of petroleum.The name paraffin implies that it contains straight hydrocarbon structure but it has branch also. Branched paraffins are called ‘Isoparafins’ and cyclic parafins are called ‘Cresines’ or ‘Isoceresies’.

Fig.3: Paraffinic  Wax
Fig.4: Micro Crystalline Wax

 

 

 

 

 

 

Pure paraffin wax dose in rubber compounding varies from 1-3 phr. Pure paraffin wax is rarely used these days in rubber industry as it has oozing character and in excess it causes blooming on green rubber components, that results in reduction in compound tack. They are frequently blended with microcrystalline wax in rubber compounding therefore.

Pure paraffin wax is an excellent electrical insulator, with an electrical resistivity of between 1013 and 1017 ohm meter. This is better than nearly all other materials except some plastics (notably teflon or polytetrafluoroethylene). It is an effective neutron moderator and was used in James Chadwick's 1932 experiments to identify the neutron. Paraffin wax (C25H52) is an excellent material to store heat, having a specific heat capacity of 2.14–2.9 J g–1 K–1 (joule per gram per kelvin) and a heat of fusion of 200–220 J g–1(joule per gram). This property is exploited in modified drywall for home building material.

Microcrystalline waxes: This is produced by de-oiling petrolatum, as part of the petroleum refining process. Microcrystalline wax contains a higher percentage of isoparaffinic (branched) hydrocarbons and naphthenic hydrocarbons. It is characterized by the fineness of its crystals in contrast to the larger crystal of paraffin wax. It consists of high molecular weight saturated aliphatic hydrocarbons with comparatively higher melting point than paraffinic wax. It is generally darker, more viscous, denser, tackier and more elastic than paraffin waxes. The elastic and adhesive characteristics of microcrystalline waxes are related to the non-straight chain components which they contain. Typical microcrystalline wax crystal structure is small and thin, making them more flexible than paraffin wax. It is commonly used in rubber formulation and cosmetic formulations.

Its usual carbon atom ranges from C40–C70 , having comparatively higher melting point (Fig.4) between 80-105 0C because they have higher number of carbon. Common dose in rubber compounding is between 1-3 phr. Some time higher dose of  100% Micro crystalline wax is difficult to process and as a result they are often blended with paraffinic wax for rubber use. Blending is also done for economical reasons as microcrystalline wax is comparatively costlier. Paraffinic wax, having smaller molecular weight bleeds faster in cured rubber article, whereas, 100% micro crystalline wax  will have inherent resistance to faster volatilization and eventually, blended wax will have an intermediate property. Refineries may also utilize blending facilities to combine paraffin and microcrystalline waxes. This type of activity is prevalent especially for industries such as tire and rubber industries.

Higher dose of antioxidant and anti ozonates are always advised to add along with microcrystalline wax because the later help slower migration of antioxidant and antiozonates on the product surface and thereby increase on the product durability against ageing process. Tire curing bladder is often blended with 1-3 phr of microcrystalline wax.

Fig.5: Polyethylene, Fig.6: Polyethylene wax
Fig.7: Chlorinated Polyethylene waxes (CPE)

Chlorinated Paraffin Wax

Upon chlorination of paraffinic wax we get Chlorinated Paraffin Wax(CPW). This is available in batch process that is processed from effective exothermic reaction. This reaction generates a by-product hydrochloric acid that is later removed out of the solution. Finally stabilizer and solution is mixed that provide the required final product, which is used in various industrial applications. With 30 to 70% chlorine and insolubility in water, these CPWs have low vapor pressure. Chlorinated Paraffin Wax is highly inert, insoluble in water and they have low vapor pressure. Generally used as plasticizers in plastic and elastomers, where flame retardant property is important.

Polyethylene waxes (PE-Wax)

Polyethylene waxes or PE-Wax is same familiar polyethylene chemical structure (Fig.5) but with lower molecular weight , generally around or less than 3000.This is a processing aid in elastomer and plastics but basically they are a form of synthetic resins. It is a white solid product (Fig.6) appears in the market as powdery, lumpy, or flaky product. It is a non-toxic product having concentrated distribution of molecular weight of 1500 with specific gravity about 0.94 with high softening point but low fusion viscosity with melting point; 112 - 118°C, melt peak 110 °C, flash point 210°C, minimum. It has excellent stability against polishing, scratch resistance, metal mark resistance, scuff resistance. PE-Wax is resistant to water and chemical materials.

 

Cabot Announces Price Hike For Speciality Carbons And Compounds

Cabot Announces Price Hike For Speciality Carbons And Compounds

Cabot Corporation has announced a comprehensive global price adjustment for its portfolio of carbon black products. These changes, which are set to take effect immediately or as soon as individual contract terms permit, will see prices rise by up to 20 percent, with the exact percentage varying according to the specific product type and the regional market. This adjustment is not limited to the speciality carbons division; it will also be applied to the offerings from the company’s speciality compounds business.

In a strategic move to address persistent market volatility, Cabot is also implementing an ongoing surcharge on top of the base price increase. The company has indicated that this additional fee will be subject to regular and ongoing evaluation, allowing for adjustments that reflect the dynamic nature of current market conditions. The driving forces behind these significant pricing actions are multifaceted, rooted in substantial disruptions to global supply chains. These disruptions are largely attributed to the ongoing conflict in the Middle East, which has had a cascading effect on logistics. Compounding this issue are the sharply rising costs associated with transportation, energy and essential raw materials.

Cabot emphasises that these necessary pricing measures are fundamental to its commitment to maintaining operational stability. By implementing these changes, the corporation aims to secure its position as a dependable partner over the long term, ensuring it can continue to supply high-integrity speciality carbons, black masterbatches and conductive compounds to its global customer base without interruption.

Kordsa Showcases Advanced Composite Technologies At JEC World 2026

Kordsa Showcases Advanced Composite Technologies At JEC World 2026

Kordsa, a subsidiary of Sabancı Holding, presented its advanced material technologies to a global audience at the JEC World 2026 trade show in Paris. The company featured its latest breakthroughs in composite technologies tailored for the aviation, energy and automotive sectors. The event also served as a platform for Kordsa to communicate its sustainable growth strategy and technological transformation to an international network of stakeholders.

Held from 10 to 12 March 2026, JEC World is recognised as the premier global event for the composites industry. By convening the entire value chain, the exhibition enabled Kordsa to prominently display its expanding role and expertise in composite materials. The company’s presence was reinforced by its international subsidiaries, including US-based Fabric Development, Inc., Textile Products, Inc. and Axiom Materials, Inc., alongside Italy’s Microtex Composites Srl., demonstrating a unified approach shaped by evolving market demands.

Among the key innovations showcased were Ceramic Matrix Composite (CMC) technologies, carbon-reinforced prepregs, thermoplastic automotive interior components and structural body parts. These solutions are engineered to deliver high performance and reduced weight while simultaneously boosting production efficiency and minimising carbon footprint. For the aviation and energy industries, the company highlighted advanced composites designed to meet stringent demands for high-temperature resistance, durability and operational reliability.

Ergun Hepvar, CEO, Kordsa, said, “JEC World is one of the most important global meeting points in the field of composite technologies. On this platform, which brings together the entire value chain of the industry, we have the opportunity to closely observe both the current state of technologies and the trends that will shape the future. This year, we clearly saw that solutions focused on sustainability, lightweighting, high performance and production efficiency are becoming increasingly decisive. At the same time, we witnessed a transformation in customer expectations towards more integrated, agile and sustainable solutions. As Kordsa, we will continue to be an active part of this transformation and to develop value-creating solutions together with our customers.”

Emphasising that Kordsa differentiates itself in composite technologies by offering an end-to-end integrated structure, from R&D and serial production to supply chain and certification processes, Hepvar further added, “The increasing demand for advanced material solutions further strengthens our position in composites. We position composite technologies as one of our two strategic focus areas in Kordsa’s future. In this field, we adopt an approach that expands technological depth, product diversity and application areas simultaneously. Composite technologies stand out as a core area shaping both Kordsa’s present and future. Our goal is to deepen our capabilities here, build a structure that generates higher added value, differentiates itself and grows together with its customers.”

Stacey Davidson

Once held up as a model for circular tyre waste management, South Africa now faces a mounting environmental and governance crisis. With millions of vehicles and thousands of waste tyres generated daily, REDISA warns that policy missteps, weak execution and leadership failures have turned a manageable system into a growing national risk.

The Recycling and Economic Development Initiative of South Africa (REDISA) called out the country’s waste tyre recycling system a ‘ticking time bomb’. The country with an estimated population of about 62 million has more than 13 million registered vehicles including roughly eight million passenger cars and generates an estimated 200,000–250,000 tonnes of waste tyres from road vehicles alone each year.

This has created a major environmental and waste-management challenge alongside rising vehicle ownership.

Commenting on the issue, Executive Director of Operations at REDISA Stacey Jansen told Tyre Trends, “Waste tyre management in South Africa has, in effect, collapsed since the Waste Management Bureau under the Department of Forestry, Fisheries and the Environment (DDFE) took over in 2017. The effect is overfull depots posing significant fire risks including the dumping and burning of tyres illegally causing harmful chemicals to seep into groundwater and causing severe air pollution.”

“Economically, a huge opportunity is being missed, in that a structured management programme geared towards recycling can not only create jobs but also contribute to the circular economy as a whole. This was precisely what REDISA did between 2013 and 2017,” she added.

She also stated that internal research has shown that a functional waste plan for just 13 waste streams could raise South Africa’s GDP growth by 1.5 percentage points. For a country struggling with unemployment and stagnation, this is an avenue that must be pursued.

REDISA alleges serious governance failures within the DFFE and the Waste Management Bureau. The first problem is that no dependable data exists.

“We all know that there is a problem, but we don’t know the extent of it. The department’s figures and reports are filled with inconsistencies and errors and this impacts any effective decision-making on how to fix the issue of waste tyre management,” said Jansen.

Secondly, she argues that there does not seem to be a realisation that the government cannot handle waste tyre management on its own as it does not have the expertise, technology or experience.

Thirdly, more headline-grabbing issues such as conservation and climate, which are important, of course, receive a lot of attention. But ground-level interventions such as waste management, while not as media-friendly, offer real and relatively immediate ways to address environmental and economic problems, she stated.

THE BOMBARDING

The Biesiesvlei depot fire in 2023 caused extensive environmental damage. Alluding to the lessons learned from the incident, Jansen said, “This is a question perhaps best posed to the DFFE. Since that disaster, we have not seen a country-wide response that puts the safety of citizens and the environment first. If something isn’t done on a national scale, more depots will burn, releasing extremely toxic pollutants into the air.”

Moreover, the auctioning of nearly R100 million (USD 5–5.5 million) worth of unused pre-processing equipment has been called an ‘admission of failure’ by REDISA. Commenting on this, Jansen said, “We wish the government could tell us how they ended up idle. Either they bought the wrong equipment or they were unable to deploy it. The right decisions were clearly not made by the leadership in the department.”

Moreover, the exclusion of small businesses and micro-collectors from the current system has also impacted tyre collection, illegal dumping and rural employment.

According to Jansen, from 2013 to 2017, REDISA managed waste tyres in South Africa. In a short space of time, it built 22 tyre collection centres, employed more than 3 000 people and created 226 small waste enterprises.

This was all funded by a management fee levied on plan subscribers (producers and importers) as part of the approved Industry Waste Tyre Plan. In February 2017, following a legislative change, the state imposed an environmental levy, which replaced the fee REDISA was collecting. The levy is still being collected today, but the producers and the citizens are not seeing their money channelled into effective waste tyre management.

In fact, more than half of the money collected is going into the general tax fund. The result has been job losses, mostly in urban areas.

REDISA also claimed that the government underspent on tyre transport due to lack of storage space. Answering how does this contradiction affect the integrity of the waste tyre management system, she said, “The department admits this underspend and gives the reason in its latest annual report. They are silent on the consequences, but it can only lead to illegal dumping and burning of tyres. If you drive by almost any informal settlement or urban fringe in South Africa, you will see dumped tyres. And this could be transformed into an asset under the right system.”

CLEAR VIEW

During her interaction, Jansen encouraged citizens and journalists to visit waste tyre depots in their communities and see if they adhere to safety standards viz-a-viz 6-metre fire breaks between heaps, 8-metre gaps to buildings and fences, maximum heap size of 10 metre x 20 metre and more.

Collectors and transporters regularly complain to REDISA that the situation at the overfull depots and dumps have worsened so much since 2017 and that they are deeply concerned.

Questioning the sustainability of the current approach, Jansen said that generating nearly 70,000 waste tyres every day makes an over-reliance on storage depots deeply flawed. “This is not sustainable at all. The only outcome will be increased air pollution, contaminated groundwater and heightened fire risks. It is an attempt to apply a band-aid to the problem without addressing its root cause,” she said.

Jansen was equally critical of the DFFE’s decision to issue tenders for 32 new depots covering close to one million square metres. According to her, the move signals more than a stop-gap response. “I would describe it as an acknowledgement of defeat and clear evidence of an inability to effectively address tyre recycling in South Africa,” she added.

Reflecting on South Africa’s earlier leadership in circular tyre waste management, Jansen said restoring that position would not require sweeping policy or structural reforms. “The DFFE does not need new frameworks or radical changes. What is required is leadership that acknowledges the scale of the crisis and a willingness to return to a model that has already proven its worth, the internationally recognised REDISA model,” she said.

The warning signs are no longer theoretical. Idle equipment, expanding depots and rising illegal dumping point to a system drifting further from circularity. Without decisive leadership and a return to proven, accountable models, South Africa risks compounding environmental damage, economic loss and public health threats, allowing a ticking time bomb to keep counting down.

Ecolomondo Retains August Brown As Risk Advisor For Shamrock Texas Project

Ecolomondo Retains August Brown As Risk Advisor For Shamrock Texas Project

Ecolomondo Corporation, a leading Canadian innovator in sustainable scrap tyre recycling technology, has engaged August Brown, LLC as an independent risk advisor. This appointment supports the planning stages for a new facility in Shamrock, Texas. The firm will conduct a validation of the project's business plan and risk management approach, a step taken in preparation for marketing the green bond that will finance the development.

The proposed Texas site will feature a six-reactor plant, replicating the company’s proprietary, modular Thermal Decomposition Process (TDP) technology currently operating at its Hawkesbury, Ontario, facility but with triple capacity. This expansion follows the successful commercialisation of Ecolomondo’s proprietary TDP technology. Local support has been secured through the Shamrock Economic Development Corporation, along with a 136-acre industrial site and long-term feedstock agreements intended to supply ongoing operations.

August Brown's role will begin with a comprehensive feasibility study examining business, market and financial risks. A subsequent phase will focus on engineering, technology validation and project execution risks. This independent review process aims to improve transparency and strengthen confidence among potential bondholders and project partners. The project represents the next phase in the company's growth strategy, replicating its proven modular technology on a larger scale.

Eliot Sorella, Executive Chairman, Ecolomondo, said, “Independent validation of our technology, projected operations and financial model for our planned Shamrock Facility is an essential step that resonates strongly with investors, lenders and potential joint-venture partners.”