DIFFERENT WAXES IN RUBBER INDUSTRY

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  • June 26, 2020
DIFFERENT WAXES IN RUBBER INDUSTRY
  • Plastic ( soft or malleable) at normal ambient temperatures
  • A melting point above approximately 45 °C.
  • A  relatively low viscosity when melted (unlike many plastics)
  • Insoluble in water
  • Hydrophobic
Fig No 1

We shall be discussing here on the waxes which are only being used in the rubber and plastic industry. Beeswax, perhaps , is the first wax which used by human in the beginning of our civilization, was one of the important renewable source of fuel. The honey comb formed by bees has typical hexagonal geometric pattern (Fig.1). Bees wax is used in tire building drum, if the rubber is too sticky, it can also be used in two roll mill to take care of rubber sticking to the rolls. It is frequently being used in the BC, MC, PC, TB  inner-tube making industry during pre-forming operation in the green stage when inner-tubes are expanded under mild air pressure just before curing in mold.

 

The main commercial source of wax is, however, crude oil but not all crude oil refiners produce wax. "Mineral" wax can also be produced from lignite. Plants, animals and even insects produce materials sold in commerce as "wax". There are five categories of waxes being used in rubber industries :

  • Bees Wax
  • Paraffin Wax - made of long-chain alkane hydrocarbons
  • Microcrystalline Wax - with very fine crystalline structure
  • Chlorinated Paraffin Wax
  • Polyethylene Wax
  • Chlorinated Polyethylene Wax

The major uses of petroleum based waxes are in rubber, cosmetics and in Candle industry. They are generally white in color but show usual brown color (Fig.2) due to contaminated with oil traces. Two types of waxes, in general, are used in rubber industry, Paraffinic wax and Microcrystalline wax. Its normal dose is 1-3 phr and high level of wax impairs low temperature flexibility and compression set. Rubber compounder considers wax as a very important processing aid because it has following advantages:

 

  • Improves mixing properties
    Fig No 2
    Petroleum Based Wax

     

  • Improves dispersion of filler and other ingredients
  • Improves extrusion properties
  • Improves upon extrudate and calendared surface finish
  • Protects surface and acts as antioxidant /antiozonate

 

 

Paraffin and Microcrystalline waxes are derived from petroleum. They are easy to recover and offer a wide range of physical properties that can often be tailored by refining processes. Most producers offer two distinct types of petroleum waxes: paraffins, which are distinguished by large, well formed crystals; and microcrystallines, which are higher melting waxes with small, irregular crystals. Microcrystalline wax contains substantial proportions of branched and cyclic saturated hydrocarbons in addition to normal alkanes.

Some producers also sell "intermediate" wax, in which the boiling range is cut where the transition in crystal size and structure occur. Petroleum wax producers also characterize wax by degree of refinement; fully refined paraffin has oil content generally less than 0.5% and fully-refined micro-crystalline less than 3%. Paraffin wax produced from petroleum is essentially a pure mixture of normal and iso-alkanes without the esters, acids, etc. found in the animal and vegetable-based waxes.

Paraffin wax (or simply "paraffin") is mostly found as a white, odorless, tasteless, waxy solid, with a typical melting point between about 47-64 °C  and having a density of around 0.9 g/cm3. It is insoluble in water, but soluble in ether, benzene, and certain esters. Paraffin is unaffected by most common chemical reagents, but burns readily. Paraffin wax is generally unbranched hydrocarbon having carbon above C17 and  are solid at room temperature. Their carbon atoms typically ranges between C17 - C30 and having typical melting point around 60°C. All paraffinic wax are recovered from fractional distillation of petroleum.The name paraffin implies that it contains straight hydrocarbon structure but it has branch also. Branched paraffins are called ‘Isoparafins’ and cyclic parafins are called ‘Cresines’ or ‘Isoceresies’.

Fig.3: Paraffinic  Wax
Fig.4: Micro Crystalline Wax

 

 

 

 

 

 

Pure paraffin wax dose in rubber compounding varies from 1-3 phr. Pure paraffin wax is rarely used these days in rubber industry as it has oozing character and in excess it causes blooming on green rubber components, that results in reduction in compound tack. They are frequently blended with microcrystalline wax in rubber compounding therefore.

Pure paraffin wax is an excellent electrical insulator, with an electrical resistivity of between 1013 and 1017 ohm meter. This is better than nearly all other materials except some plastics (notably teflon or polytetrafluoroethylene). It is an effective neutron moderator and was used in James Chadwick's 1932 experiments to identify the neutron. Paraffin wax (C25H52) is an excellent material to store heat, having a specific heat capacity of 2.14–2.9 J g–1 K–1 (joule per gram per kelvin) and a heat of fusion of 200–220 J g–1(joule per gram). This property is exploited in modified drywall for home building material.

Microcrystalline waxes: This is produced by de-oiling petrolatum, as part of the petroleum refining process. Microcrystalline wax contains a higher percentage of isoparaffinic (branched) hydrocarbons and naphthenic hydrocarbons. It is characterized by the fineness of its crystals in contrast to the larger crystal of paraffin wax. It consists of high molecular weight saturated aliphatic hydrocarbons with comparatively higher melting point than paraffinic wax. It is generally darker, more viscous, denser, tackier and more elastic than paraffin waxes. The elastic and adhesive characteristics of microcrystalline waxes are related to the non-straight chain components which they contain. Typical microcrystalline wax crystal structure is small and thin, making them more flexible than paraffin wax. It is commonly used in rubber formulation and cosmetic formulations.

Its usual carbon atom ranges from C40–C70 , having comparatively higher melting point (Fig.4) between 80-105 0C because they have higher number of carbon. Common dose in rubber compounding is between 1-3 phr. Some time higher dose of  100% Micro crystalline wax is difficult to process and as a result they are often blended with paraffinic wax for rubber use. Blending is also done for economical reasons as microcrystalline wax is comparatively costlier. Paraffinic wax, having smaller molecular weight bleeds faster in cured rubber article, whereas, 100% micro crystalline wax  will have inherent resistance to faster volatilization and eventually, blended wax will have an intermediate property. Refineries may also utilize blending facilities to combine paraffin and microcrystalline waxes. This type of activity is prevalent especially for industries such as tire and rubber industries.

Higher dose of antioxidant and anti ozonates are always advised to add along with microcrystalline wax because the later help slower migration of antioxidant and antiozonates on the product surface and thereby increase on the product durability against ageing process. Tire curing bladder is often blended with 1-3 phr of microcrystalline wax.

Fig.5: Polyethylene, Fig.6: Polyethylene wax
Fig.7: Chlorinated Polyethylene waxes (CPE)

Chlorinated Paraffin Wax

Upon chlorination of paraffinic wax we get Chlorinated Paraffin Wax(CPW). This is available in batch process that is processed from effective exothermic reaction. This reaction generates a by-product hydrochloric acid that is later removed out of the solution. Finally stabilizer and solution is mixed that provide the required final product, which is used in various industrial applications. With 30 to 70% chlorine and insolubility in water, these CPWs have low vapor pressure. Chlorinated Paraffin Wax is highly inert, insoluble in water and they have low vapor pressure. Generally used as plasticizers in plastic and elastomers, where flame retardant property is important.

Polyethylene waxes (PE-Wax)

Polyethylene waxes or PE-Wax is same familiar polyethylene chemical structure (Fig.5) but with lower molecular weight , generally around or less than 3000.This is a processing aid in elastomer and plastics but basically they are a form of synthetic resins. It is a white solid product (Fig.6) appears in the market as powdery, lumpy, or flaky product. It is a non-toxic product having concentrated distribution of molecular weight of 1500 with specific gravity about 0.94 with high softening point but low fusion viscosity with melting point; 112 - 118°C, melt peak 110 °C, flash point 210°C, minimum. It has excellent stability against polishing, scratch resistance, metal mark resistance, scuff resistance. PE-Wax is resistant to water and chemical materials.

 

Trinseo Launches 4th-Gen Binder To Power Longer-Range EVs And Reliable Energy Storage

Trinseo Launches 4th-Gen Binder To Power Longer-Range EVs And Reliable Energy Storage

Trinseo has launched the Fourth-Generation SBR Binder Platform, designed to meet the evolving demands of electric vehicle and battery energy storage systems. This new technology underscores the company’s commitment to advancing high-performance materials for the global energy transition.

Created in close partnership with battery producers, the platform leverages sophisticated polymer science to deliver stronger electrode adhesion, enhanced energy density and greater overall durability. It achieves up to thirty percent higher peel strength than previous binder technologies, which facilitates thicker electrode coatings and faster manufacturing speeds – critical factors for improving battery capacity and extending vehicle range. The first offering under this platform, VOLTABOND 109 Latex Binder, provides exceptional versatility, performing reliably across various anode materials and supporting diverse cell designs and production environments.

In addition to boosting performance, the platform ensures improved high-temperature stability and reduced internal resistance, contributing to faster charging and long-term operational reliability. With manufacturing capabilities established across Asia-Pacific, Europe, and North America, Trinseo reinforces both supply chain resilience and regional support for battery producers worldwide.

This fourth-generation system is built upon decades of expertise in emulsion polymerization, setting the stage for future product developments tailored to different segments of the battery market.

Andre Hugentobler, Global VP Technology and Innovation, said, “Our Fourth-Generation Binder Platform represents a leap forward in materials innovation for both EV and ESS markets. It demonstrates how Trinseo’s polymer expertise and global manufacturing capabilities enable our customers to accelerate the next wave of electrification – safely, efficiently and at scale.”

Arthas Yang, Senior Vice President, Latex Binders, said, “This platform positions Trinseo to deliver differentiated solutions across multiple customer tiers and market segments. It reflects our ongoing investment in high-growth, high-value markets and our commitment to advancing mobility and energy solutions.”

Flexsys Develops First Viable Industry Alternative to 6PPD in Major Breakthrough for Tyre Chemistry

Flexsys Develops First Viable Industry Alternative to 6PPD in Major Breakthrough for Tyre Chemistry

Flexsys has created what it says is the tyre industry’s first practical and scalable alternative to 6PPD, marking a major step toward replacing a chemical used for decades but now under regulatory pressure.

The company said the new antidegradant is the result of several years of research and testing with federal laboratories, independent scientific groups and tyre makers. Early results show the material could match the performance and safety of 6PPD while avoiding the environmental risks linked to 6PPD-quinone, a transformation product identified in 2020.

Flexsys said the new chemistry provides the short- and long-term protection needed to stop tyres cracking or ageing. It is also designed to fit into existing rubber compounds with minimal changes, which could help manufacturers adopt it quickly. The company added that the product meets environmental and regulatory benchmarks, including criteria set by the Washington State Department of Ecology.

Importantly, the new molecule is not part of the “PPD” family, meaning it does not form quinone during use. Flexsys said this would remove the environmental impact associated with 6PPD-quinone. The company is also using many of the same intermediate chemicals already used in 6PPD production. This could allow manufacturers to rely on existing factory assets and speed the shift to the new technology.

“This achievement reflects our unwavering commitment to responsible innovation, built on decades of expertise in tire protection chemistry,” said Carl Brech, Chief Executive Officer of Flexsys. “Our solution is formulated to deliver the performance and reliability that tire makers expect and is designed for future environmental and regulatory standards.”

6PPD has been essential to tyre durability for 50 years. But studies published in 2020 showed that 6PPD-quinone could harm aquatic species, including coho salmon. Regulators and tyre producers have been looking for a safer option since then. Flexsys said its new antidegradant meets this challenge without reducing tyre safety.

“Our team set out to develop a next-generation antidegradant that meets the tire industry’s highest performance standards without compromising tire safety, while also reducing toxicity,” said Neil Smith, Chief Technology and Sustainability Officer. “I could not be more proud of the perseverance and dedication of the Flexsys R&D team. Our group has been highly motivated by both the technical challenges of this project as well as the positive societal impact that this work will ultimately have.”

Flexsys acknowledged support from the Sustainable Polymers Tech Hub in Akron, Ohio, part of the U.S. EDA Tech Hubs programme.

The company is now working on process optimisation to allow large-scale production. It is also in discussions with regulators around the world to secure approvals for commercial use. Testing with tyre makers is continuing.

“Flexsys is helping set the direction of the tire industry for the coming decades with this development,” Brech said. “We will continue to work tirelessly to bring this breakthrough to the market as soon as possible.”

Wacker, SICO Open China R&D Centre to Speed Rollout of Specialty Silanes

Wacker, SICO Open China R&D Centre to Speed Rollout of Specialty Silanes

Wacker Chemie AG has strengthened its position in China’s fast-growing market for silicone specialities by opening a new application development centre with joint-venture partner SICO Performance Material in the eastern city of Jining.

The 2,300-square-metre facility brings together several laboratories focused on organofunctional silanes, which are used as high-performance additives in plastics, coatings and adhesives. By locating the centre next to SICO’s production and scale-up lines, Wacker aims to shorten development cycles and move new products into the market more quickly. The companies said investment in the site is in the mid-six-figure euro range.

Tom Koini, who leads Wacker’s silicones division, said the opening marks an important step in its China strategy. “As a provider of innovative silicone specialties and solutions, we can use this development center to achieve a key milestone for our business in China. Our focus is on high-margin specialty silanes, for which demand in China is rising continuously. This investment together with our partner SICO strengthens our presence and commitment to the region,” he said.

Wacker, which took a majority stake in SICO in 2022, is seeking to build a larger share of China’s specialty chemicals market, where demand for hybrid polymers has increased for years. These materials help improve the mechanical and chemical properties of adhesives, sealants, coatings and engineered plastics, all of which are used in sectors such as electric mobility, electronics and power equipment.

At the opening ceremony, SICO General Manager Kevin Qu called the centre an investment in the long term. “We can now pool all of our silane expertise here at our application development centre. This know-how ranges from chemical product properties and supply chain matters through to questions of process engineering and current marketing trends. We will leverage this in-depth knowledge to develop forward-looking innovations for our customers. This marks a new chapter of success in the history of our joint venture,” he said.

The companies said the centre will act as a link between research, technical service and manufacturing teams. Scientists will focus on developing additives, adhesion promoters and stabilisers based on organofunctional silanes and functional silicone fluids.

ANRPC Publishes Monthly NR Statistical Report For October 2025

ANRPC Publishes Monthly NR Statistical Report For October 2025

The Association of Natural Rubber Producing Countries (ANRPC) has released its Monthly NR Statistical Report for October 2025, providing an overview of key developments in the global natural rubber sector.

According to the report, the global natural rubber market in October was characterised by a distinct bearish trend in pricing. This decline can primarily due to a significant surge in production and export activities, which were initially stimulated by the higher prices seen earlier in the year. Meanwhile, overall demand has remained relatively subdued.

Looking ahead to the full year, projections indicate a modest 1.3 percent increase in global production for 2025, a figure that follows a recent downward revision for Indonesia. On the demand side, consumption is anticipated to grow by a slight 0.8 percent, influenced by an upward adjustment to Indonesia's consumption data. Despite the current price pressures, market sentiment shows some mixed signs of improvement, particularly within the tyre trade of certain specific markets.