• Plastic ( soft or malleable) at normal ambient temperatures
• A melting point above approximately 45 °C.
• A  relatively low viscosity when melted (unlike many plastics)
• Insoluble in water
• Hydrophobic

We shall be discussing here on the waxes which are only being used in the rubber and plastic industry. Beeswax, perhaps , is the first wax which used by human in the beginning of our civilization, was one of the important renewable source of fuel. The honey comb formed by bees has typical hexagonal geometric pattern (Fig.1). Bees wax is used in tire building drum, if the rubber is too sticky, it can also be used in two roll mill to take care of rubber sticking to the rolls. It is frequently being used in the BC, MC, PC, TB  inner-tube making industry during pre-forming operation in the green stage when inner-tubes are expanded under mild air pressure just before curing in mold.

The main commercial source of wax is, however, crude oil but not all crude oil refiners produce wax. "Mineral" wax can also be produced from lignite. Plants, animals and even insects produce materials sold in commerce as "wax". There are five categories of waxes being used in rubber industries :

• Bees Wax
• Paraffin Wax - made of long-chain alkane hydrocarbons
• Microcrystalline Wax - with very fine crystalline structure
• Chlorinated Paraffin Wax
• Polyethylene Wax
• Chlorinated Polyethylene Wax

The major uses of petroleum based waxes are in rubber, cosmetics and in Candle industry. They are generally white in color but show usual brown color (Fig.2) due to contaminated with oil traces. Two types of waxes, in general, are used in rubber industry, Paraffinic wax and Microcrystalline wax. Its normal dose is 1-3 phr and high level of wax impairs low temperature flexibility and compression set. Rubber compounder considers wax as a very important processing aid because it has following advantages:

• Improves mixing properties

  

   

• Improves dispersion of filler and other ingredients
• Improves extrusion properties
• Improves upon extrudate and calendared surface finish
• Protects surface and acts as antioxidant /antiozonate

Paraffin and Microcrystalline waxes are derived from petroleum. They are easy to recover and offer a wide range of physical properties that can often be tailored by refining processes. Most producers offer two distinct types of petroleum waxes: paraffins, which are distinguished by large, well formed crystals; and microcrystallines, which are higher melting waxes with small, irregular crystals. Microcrystalline wax contains substantial proportions of branched and cyclic saturated hydrocarbons in addition to normal alkanes.

Some producers also sell "intermediate" wax, in which the boiling range is cut where the transition in crystal size and structure occur. Petroleum wax producers also characterize wax by degree of refinement; fully refined paraffin has oil content generally less than 0.5% and fully-refined micro-crystalline less than 3%. Paraffin wax produced from petroleum is essentially a pure mixture of normal and iso-alkanes without the esters, acids, etc. found in the animal and vegetable-based waxes.

Paraffin wax (or simply "paraffin") is mostly found as a white, odorless, tasteless, waxy solid, with a typical melting point between about 47-64 °C  and having a density of around 0.9 g/cm³. It is insoluble in water, but soluble in ether, benzene, and certain esters. Paraffin is unaffected by most common chemical reagents, but burns readily. Paraffin wax is generally unbranched hydrocarbon having carbon above C₁₇ and  are solid at room temperature. Their carbon atoms typically ranges between C₁₇ - C₃₀ and having typical melting point around 60°C. All paraffinic wax are recovered from fractional distillation of petroleum.The name paraffin implies that it contains straight hydrocarbon structure but it has branch also. Branched paraffins are called ‘Isoparafins’ and cyclic parafins are called ‘Cresines’ or ‘Isoceresies’.

Pure paraffin wax dose in rubber compounding varies from 1-3 phr. Pure paraffin wax is rarely used these days in rubber industry as it has oozing character and in excess it causes blooming on green rubber components, that results in reduction in compound tack. They are frequently blended with microcrystalline wax in rubber compounding therefore.

Pure paraffin wax is an excellent electrical insulator, with an electrical resistivity of between 10¹³ and 10¹⁷ ohm meter. This is better than nearly all other materials except some plastics (notably teflon or polytetrafluoroethylene). It is an effective neutron moderator and was used in James Chadwick's 1932 experiments to identify the neutron. Paraffin wax (C₂₅H₅₂) is an excellent material to store heat, having a specific heat capacity of 2.14–2.9 J g^–1 K^–1 (joule per gram per kelvin) and a heat of fusion of 200–220 J g^–1(joule per gram). This property is exploited in modified drywall for home building material.

Microcrystalline waxes: This is produced by de-oiling petrolatum, as part of the petroleum refining process. Microcrystalline wax contains a higher percentage of isoparaffinic (branched) hydrocarbons and naphthenic hydrocarbons. It is characterized by the fineness of its crystals in contrast to the larger crystal of paraffin wax. It consists of high molecular weight saturated aliphatic hydrocarbons with comparatively higher melting point than paraffinic wax. It is generally darker, more viscous, denser, tackier and more elastic than paraffin waxes. The elastic and adhesive characteristics of microcrystalline waxes are related to the non-straight chain components which they contain. Typical microcrystalline wax crystal structure is small and thin, making them more flexible than paraffin wax. It is commonly used in rubber formulation and cosmetic formulations.

Its usual carbon atom ranges from C₄₀–C₇₀ , having comparatively higher melting point (Fig.4) between 80-105 ⁰C because they have higher number of carbon. Common dose in rubber compounding is between 1-3 phr. Some time higher dose of  100% Micro crystalline wax is difficult to process and as a result they are often blended with paraffinic wax for rubber use. Blending is also done for economical reasons as microcrystalline wax is comparatively costlier. Paraffinic wax, having smaller molecular weight bleeds faster in cured rubber article, whereas, 100% micro crystalline wax  will have inherent resistance to faster volatilization and eventually, blended wax will have an intermediate property. Refineries may also utilize blending facilities to combine paraffin and microcrystalline waxes. This type of activity is prevalent especially for industries such as tire and rubber industries.

Higher dose of antioxidant and anti ozonates are always advised to add along with microcrystalline wax because the later help slower migration of antioxidant and antiozonates on the product surface and thereby increase on the product durability against ageing process. Tire curing bladder is often blended with 1-3 phr of microcrystalline wax.

Chlorinated Paraffin Wax

Upon chlorination of paraffinic wax we get Chlorinated Paraffin Wax(CPW). This is available in batch process that is processed from effective exothermic reaction. This reaction generates a by-product hydrochloric acid that is later removed out of the solution. Finally stabilizer and solution is mixed that provide the required final product, which is used in various industrial applications. With 30 to 70% chlorine and insolubility in water, these CPWs have low vapor pressure. Chlorinated Paraffin Wax is highly inert, insoluble in water and they have low vapor pressure. Generally used as plasticizers in plastic and elastomers, where flame retardant property is important.

Polyethylene waxes (PE-Wax)

Polyethylene waxes or PE-Wax is same familiar polyethylene chemical structure (Fig.5) but with lower molecular weight , generally around or less than 3000.This is a processing aid in elastomer and plastics but basically they are a form of synthetic resins. It is a white solid product (Fig.6) appears in the market as powdery, lumpy, or flaky product. It is a non-toxic product having concentrated distribution of molecular weight of 1500 with specific gravity about 0.94 with high softening point but low fusion viscosity with melting point; 112 - 118°C, melt peak 110 °C, flash point 210°C, minimum. It has excellent stability against polishing, scratch resistance, metal mark resistance, scuff resistance. PE-Wax is resistant to water and chemical materials.

Kraton Corporation, a leading global producer of speciality polymers and high-value biobased products derived from by-products of pine wood pulping, has received an International Sustainability and Carbon Certification (ISCC) PLUS certification for its manufacturing facility in Niort, France.

Kraton can now supply 100 percent ISCC PLUS-certified AMS and AMS Phenolics resins using a mass balance attribution approach thanks to the certification. Kraton's dedication to promoting the biobased and circular economy is further demonstrated by the Niort facility's accreditation. Kraton is committed to lowering carbon emissions and accelerating the shift to a more sustainable future by empowering clients to include more environmentally friendly products into their supply chains.

An independent multi-stakeholder project, the International Sustainability and Carbon Certification (ISCC) is a leading certification method that guarantees accurate mass-balancing bookkeeping and reporting of renewable and recycled materials across the supply chain.

Lana Culbert, Kraton Pine Chemicals VP of Marketing, said, “Our SYLVARES™ and SYLVATRAXX™ brands feature a range of high-performance AMS and AMS Phenolics resins used in speciality adhesives and tyre applications. Our ISCC PLUS journey began in 2021 with the certification of our Sandarne, Sweden facility. Earning this certification for our Niort plant marks a significant milestone, further expanding our portfolio of sustainable solutions.”

Sumitomo Rubber Industries, Ltd. has said that it has clarified the process of rubber breakdown, a crucial element that affects tyre longevity, through joint research with Professor Gert Heinrich at Dresden University of Technology (Saxony State, Germany).

In a special session called ‘Combining Physics, Chemistry & Engineering of Rubber: A Symposium in Honor of Charles Goodyear Medalist Gert Heinrich’, which was held in honour of the Professor's medal-winning achievement, the findings were presented in an invited talk at the American Chemical Society, Rubber division, ACS 2025 Spring Technical Meeting held in Orlando, Florida, US, on 6 and 7 March. Professor Heinrich is a member of the Leibniz Institute of Polymer Research Dresden, which took part in the collaborative effort.

Tyre durability is determined by cracking processes, which result in the development of cracks and rips in a rubber substance. The endurance of rubber was previously mostly assessed using tearing tests, but there were still numerous unanswered concerns regarding the microscale structural alterations at the crack tip. This effort identified a factor that determines the start and propagation of cracks in rubber by analysing the force applied to a fracture tip using a simulation approach. In rubber, a crack tip undergoes dilatation deformation to create voids, or microvoids within the item. The fracture gets worse as the voids expand and come together. It was also discovered that the tension focused on the fracture tip is lessened when voids emerge.

The German Rubber Industry Association (Wdk) is advocating for a thorough and legally enforceable regulation of the end-of-waste status for Germany and the whole of Europe. The association is pusing for the circular economy to be strengthened for tyres.

Valuable secondary raw materials are still legally regarded as waste since there are no consistent standards for the end-of-waste status, according to Stephan Rau, Technical Director of the WDW. This restricts the market integration of sustainable recycled materials, impedes investments and creates legal uncertainties. “We call for a comprehensive and binding end-of-waste regulation for Germany and the whole of Europe to strengthen the recycling sector, facilitate investment in modern technologies, and sustainably reduce the CO₂ footprint of the rubber and tire industry,” he said.

In order to adhere to the prescribed waste hierarchy and stop illicit exports, Rau also emphasised that lawmakers must quantitatively and openly document waste tyre flows. He added that waste tyres should only be gathered by approved disposal companies and pre-sorted based on their intended use.

On the important role of mechanically recycled tyre granules and powder, Rau said, "This is an important secondary raw material that is already used in a variety of durable and safe products. A clearly defined end to its waste status must be made more economically viable. To ensure the market success of tyre granules, a risk-based approach to assessing chemical ingredients is essential. Binding limit values ​​must be assessed using a migration analysis, i.e. based on their bioavailability. Second, the use of tyre granule products must become mandatory in the construction industry and infrastructure projects. The goal is clear: Recycling must be economically viable."

Kuraray, a global speciality chemicals company and one of the largest suppliers of industrial polymers and synthetic microfibres, has received ISCC PLUS certification for its thermoplastic elastomers SEPTON and HYBRAR as well as Liquid Rubber produced at the Company’s Kashima Plant at Ibaraki Prefecture.

ISCC PLUS makes sure that certified products, such biomass and recycled raw materials, are appropriately handled throughout their supply chains, including the manufacturing process, by applying the mass-balance technique.

In the five years preceding up to its centenary in 2026, Kuraray is carrying out its medium-term management strategy, PASSION 2026. In order to achieve the long-term Kuraray Vision 2026 of being a speciality chemical company that grows sustainably by integrating new foundational platforms into its own technologies and contributing to customers, society and the planet, the company will keep growing its range of products that improve the natural and living environments.