DIFFERENT WAXES IN RUBBER INDUSTRY

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  • June 26, 2020
DIFFERENT WAXES IN RUBBER INDUSTRY
  • Plastic ( soft or malleable) at normal ambient temperatures
  • A melting point above approximately 45 °C.
  • A  relatively low viscosity when melted (unlike many plastics)
  • Insoluble in water
  • Hydrophobic
Fig No 1

We shall be discussing here on the waxes which are only being used in the rubber and plastic industry. Beeswax, perhaps , is the first wax which used by human in the beginning of our civilization, was one of the important renewable source of fuel. The honey comb formed by bees has typical hexagonal geometric pattern (Fig.1). Bees wax is used in tire building drum, if the rubber is too sticky, it can also be used in two roll mill to take care of rubber sticking to the rolls. It is frequently being used in the BC, MC, PC, TB  inner-tube making industry during pre-forming operation in the green stage when inner-tubes are expanded under mild air pressure just before curing in mold.

 

The main commercial source of wax is, however, crude oil but not all crude oil refiners produce wax. "Mineral" wax can also be produced from lignite. Plants, animals and even insects produce materials sold in commerce as "wax". There are five categories of waxes being used in rubber industries :

  • Bees Wax
  • Paraffin Wax - made of long-chain alkane hydrocarbons
  • Microcrystalline Wax - with very fine crystalline structure
  • Chlorinated Paraffin Wax
  • Polyethylene Wax
  • Chlorinated Polyethylene Wax

The major uses of petroleum based waxes are in rubber, cosmetics and in Candle industry. They are generally white in color but show usual brown color (Fig.2) due to contaminated with oil traces. Two types of waxes, in general, are used in rubber industry, Paraffinic wax and Microcrystalline wax. Its normal dose is 1-3 phr and high level of wax impairs low temperature flexibility and compression set. Rubber compounder considers wax as a very important processing aid because it has following advantages:

 

  • Improves mixing properties
    Fig No 2
    Petroleum Based Wax

     

  • Improves dispersion of filler and other ingredients
  • Improves extrusion properties
  • Improves upon extrudate and calendared surface finish
  • Protects surface and acts as antioxidant /antiozonate

 

 

Paraffin and Microcrystalline waxes are derived from petroleum. They are easy to recover and offer a wide range of physical properties that can often be tailored by refining processes. Most producers offer two distinct types of petroleum waxes: paraffins, which are distinguished by large, well formed crystals; and microcrystallines, which are higher melting waxes with small, irregular crystals. Microcrystalline wax contains substantial proportions of branched and cyclic saturated hydrocarbons in addition to normal alkanes.

Some producers also sell "intermediate" wax, in which the boiling range is cut where the transition in crystal size and structure occur. Petroleum wax producers also characterize wax by degree of refinement; fully refined paraffin has oil content generally less than 0.5% and fully-refined micro-crystalline less than 3%. Paraffin wax produced from petroleum is essentially a pure mixture of normal and iso-alkanes without the esters, acids, etc. found in the animal and vegetable-based waxes.

Paraffin wax (or simply "paraffin") is mostly found as a white, odorless, tasteless, waxy solid, with a typical melting point between about 47-64 °C  and having a density of around 0.9 g/cm3. It is insoluble in water, but soluble in ether, benzene, and certain esters. Paraffin is unaffected by most common chemical reagents, but burns readily. Paraffin wax is generally unbranched hydrocarbon having carbon above C17 and  are solid at room temperature. Their carbon atoms typically ranges between C17 - C30 and having typical melting point around 60°C. All paraffinic wax are recovered from fractional distillation of petroleum.The name paraffin implies that it contains straight hydrocarbon structure but it has branch also. Branched paraffins are called ‘Isoparafins’ and cyclic parafins are called ‘Cresines’ or ‘Isoceresies’.

Fig.3: Paraffinic  Wax
Fig.4: Micro Crystalline Wax

 

 

 

 

 

 

Pure paraffin wax dose in rubber compounding varies from 1-3 phr. Pure paraffin wax is rarely used these days in rubber industry as it has oozing character and in excess it causes blooming on green rubber components, that results in reduction in compound tack. They are frequently blended with microcrystalline wax in rubber compounding therefore.

Pure paraffin wax is an excellent electrical insulator, with an electrical resistivity of between 1013 and 1017 ohm meter. This is better than nearly all other materials except some plastics (notably teflon or polytetrafluoroethylene). It is an effective neutron moderator and was used in James Chadwick's 1932 experiments to identify the neutron. Paraffin wax (C25H52) is an excellent material to store heat, having a specific heat capacity of 2.14–2.9 J g–1 K–1 (joule per gram per kelvin) and a heat of fusion of 200–220 J g–1(joule per gram). This property is exploited in modified drywall for home building material.

Microcrystalline waxes: This is produced by de-oiling petrolatum, as part of the petroleum refining process. Microcrystalline wax contains a higher percentage of isoparaffinic (branched) hydrocarbons and naphthenic hydrocarbons. It is characterized by the fineness of its crystals in contrast to the larger crystal of paraffin wax. It consists of high molecular weight saturated aliphatic hydrocarbons with comparatively higher melting point than paraffinic wax. It is generally darker, more viscous, denser, tackier and more elastic than paraffin waxes. The elastic and adhesive characteristics of microcrystalline waxes are related to the non-straight chain components which they contain. Typical microcrystalline wax crystal structure is small and thin, making them more flexible than paraffin wax. It is commonly used in rubber formulation and cosmetic formulations.

Its usual carbon atom ranges from C40–C70 , having comparatively higher melting point (Fig.4) between 80-105 0C because they have higher number of carbon. Common dose in rubber compounding is between 1-3 phr. Some time higher dose of  100% Micro crystalline wax is difficult to process and as a result they are often blended with paraffinic wax for rubber use. Blending is also done for economical reasons as microcrystalline wax is comparatively costlier. Paraffinic wax, having smaller molecular weight bleeds faster in cured rubber article, whereas, 100% micro crystalline wax  will have inherent resistance to faster volatilization and eventually, blended wax will have an intermediate property. Refineries may also utilize blending facilities to combine paraffin and microcrystalline waxes. This type of activity is prevalent especially for industries such as tire and rubber industries.

Higher dose of antioxidant and anti ozonates are always advised to add along with microcrystalline wax because the later help slower migration of antioxidant and antiozonates on the product surface and thereby increase on the product durability against ageing process. Tire curing bladder is often blended with 1-3 phr of microcrystalline wax.

Fig.5: Polyethylene, Fig.6: Polyethylene wax
Fig.7: Chlorinated Polyethylene waxes (CPE)

Chlorinated Paraffin Wax

Upon chlorination of paraffinic wax we get Chlorinated Paraffin Wax(CPW). This is available in batch process that is processed from effective exothermic reaction. This reaction generates a by-product hydrochloric acid that is later removed out of the solution. Finally stabilizer and solution is mixed that provide the required final product, which is used in various industrial applications. With 30 to 70% chlorine and insolubility in water, these CPWs have low vapor pressure. Chlorinated Paraffin Wax is highly inert, insoluble in water and they have low vapor pressure. Generally used as plasticizers in plastic and elastomers, where flame retardant property is important.

Polyethylene waxes (PE-Wax)

Polyethylene waxes or PE-Wax is same familiar polyethylene chemical structure (Fig.5) but with lower molecular weight , generally around or less than 3000.This is a processing aid in elastomer and plastics but basically they are a form of synthetic resins. It is a white solid product (Fig.6) appears in the market as powdery, lumpy, or flaky product. It is a non-toxic product having concentrated distribution of molecular weight of 1500 with specific gravity about 0.94 with high softening point but low fusion viscosity with melting point; 112 - 118°C, melt peak 110 °C, flash point 210°C, minimum. It has excellent stability against polishing, scratch resistance, metal mark resistance, scuff resistance. PE-Wax is resistant to water and chemical materials.

 

HS HYOSUNG Powers Vietnam Subsidiary With 17.5-MWp Solar Power Installation

HS HYOSUNG Powers Vietnam Subsidiary With 17.5-MWp Solar Power Installation

HS HYOSUNG ADVANCED MATERIALS has completed and commenced operation of a 17.5-MWp rooftop solar power installation at its facility in Vietnam’s Nhon Trach Industrial Park, located within Dong Nai Province. This marks a significant step in the company’s broader effort to reshape its Vietnam operations – its largest global manufacturing base for tyre cords and technical yarns – into what it terms a ‘Smart Green Factory’. By merging renewable energy infrastructure with digital energy management systems, developed in partnership with the energy IT specialist Nuriflex, the firm is positioning this site at the forefront of its transition towards becoming a global eco-friendly manufacturing hub.

A key element of this transformation is the deployment of an Internet of Things based energy management system, which allows for real-time oversight of electricity generation and equipment performance. This digital layer not only streamlines operational efficiency but also contributes to greater equipment reliability and overall productivity gains, ensuring that the integration of renewable energy delivers tangible improvements beyond simple power generation.

With further solar installations set to be completed by August, total rooftop capacity at the Nhon Trach site will reach 37.5 MWp. Once fully operational in the latter half of the year, HS HYOSUNG ADVANCED MATERIALS anticipates annual electricity cost savings exceeding KRW 6 billion (approximately USD 3.94 million), bolstering its cost competitiveness. The expansion is also expected to deliver meaningful reductions in greenhouse gas emissions, reinforcing the company’s long-term commitment to sustainable management practices.

Through advanced energy IoT solutions, the Vietnam subsidiary now systematically manages carbon reduction data generated from its solar power operations. This capability enables a more structured response to rising demands from major global customers – including Michelin, Bridgestone, Goodyear, Continental and Pirelli – for verified renewable energy usage and carbon emissions information. By strengthening its ESG performance across the supply chain, the company is leveraging its solar infrastructure and smart energy management not merely as facility investments but as strategic tools to enhance environmental responsibility and competitiveness in a market where sustainable value chains are increasingly essential.

“Starting with our Vietnam production base, we are simultaneously promoting renewable energy transition and energy efficiency improvements across our operations. By expanding solar power facilities, we will strengthen both cost competitiveness and ESG capabilities while proactively responding to the evolving requirements of our global customers,” said an official from HS HYOSUNG ADVANCED MATERIALS.

ANRPC Publishes Monthly NR Statistical Report For February 2026

The Association of Natural Rubber Producing Countries (ANRPC) has released its Monthly NR Statistical Report for February 2026, detailing a period of significant market activity influenced by geopolitical tensions, macroeconomic changes and shifting supply-demand dynamics within the global natural rubber sector.

As per the report, global natural rubber production for 2026 is forecast to reach 15.324 million tonnes, a 2.2 percent increase from the 14.996 million tonnes recorded in 2025. February output alone is projected at 994,000 tonnes, marking a 3.4 percent year-on-year rise due to favourable weather and higher rubber prices. Despite this overall growth, production trends vary among member nations. While Thailand is expected to remain the top producer, Indonesia and Vietnam face short-term constraints from structural and agronomic issues. Meanwhile, Malaysia is advancing efforts to restore abandoned plantations, with the Rubber Production Incentive activated in Sarawak and Sabah and the Malaysian Rubber Board targeting the rehabilitation of 4,137 hectares of idle land in 2026.

Physical and futures markets saw notable price increases across major grades in February. In Kuala Lumpur, SMR-20 averaged USD 2.01 per kilogramme, a 5.13 percent monthly gain, while STR-20 in Bangkok rose 5.12 percent to USD 2.11 per kilogramme. Sheet rubber grades also strengthened, with RSS-3 increasing 7.84 percent to USD 2.35 per kilogramme and RSS-4 in Kottayam surging 10.38 percent to USD 2.34 per kilogramme. Centrifuged latex in Kuala Lumpur closed the month at USD 1.61 per kilogramme. Futures mirrored this firming trend, as the Shanghai Futures Exchange May 2026 contract averaged roughly 16,508 CNY (approximately USD 2,388) per tonne and the SGX contract averaged USD 1.92 per kilogramme, supported by strong demand and tightening supply expectations ahead of the seasonal low-yield period from February to May.

Crude oil volatility added further complexity, with Brent averaging USD 70.89 per barrel in February – up 6.43 percent from January – before spiking to approximately USD 104 per barrel in early March following military actions in the Middle East and the closure of the Strait of Hormuz, a conduit for nearly 20 percent of global oil supply. This has introduced a risk premium with implications for synthetic rubber competitiveness and natural rubber demand. Currency shifts also play a role, as the Malaysian Ringgit appreciated modestly to 3.89 MYR per USD and the Thai Baht strengthened to around 31.08 THB per USD by late February, affecting trade competitiveness. Looking ahead, rising automotive production, especially of new energy vehicles in China, India and Southeast Asia, is expected to sustain demand and support prices. However, risks persist from US-China trade tensions, Middle East geopolitical instability, weather uncertainties during the low-yield season and currency fluctuations tied to US monetary policy, all of which could disrupt supply chains and export revenues.

Tokyo Zairyo Expands Indian Operations With New Chennai Branch Office

Tokyo Zairyo Expands Indian Operations With New Chennai Branch Office

Tokyo Zairyo Co., Ltd., a wholly owned subsidiary of Zeon Corporation, marked a significant milestone in November 2025 by establishing a new branch office in Chennai, Tamil Nadu, India. Following the completion of all necessary preparations, this location has now commenced full-scale operations. The move represents a deliberate effort to broaden the company’s commercial reach across the Indian market while simultaneously constructing an organizational structure capable of responding with greater agility to the evolving and increasingly diverse requirements of its customers.

This southern expansion comes approximately 15 years after the company first established its Indian subsidiary, Tokyo Zairyo (India) Pvt. Ltd., with an office in Gurugram, Haryana, in 2011. By positioning a second office in Chennai, the firm now operates a coordinated network spanning the northern and southern regions of the country. Close collaboration between the two locations is intended to strengthen information services and enhance user support, leveraging both internal capabilities and external partnerships to better serve Japanese automotive parts manufacturers and processors operating throughout India.

Through this dual-office structure, Tokyo Zairyo is poised to advance its core business of purchasing and selling a broad spectrum of materials, including rubber, resins and elastomers. The synchronised operations in Gurugram and Chennai enable the company to deliver more responsive support, ensuring that clients across the Indian automotive supply chain benefit from efficient service and a reliable supply of essential materials.

Kuraray Announces Price Hike For Liquid Rubber And ISOBAM

Kuraray Announces Price Hike For Liquid Rubber And ISOBAM

Kuraray Co., Ltd. has announced a comprehensive global price adjustment for its portfolio of Liquid Rubber products and ISOBAM alkaline water-soluble polymer. These changes, which are set to take effect on 16 April 2026, will see prices rise by at least USD 2 per kg.

The driving forces behind these significant pricing actions are multifaceted, rooted in substantial disruptions to global supply chains. These disruptions are largely attributed to the ongoing conflict in the Middle East, which has had a cascading effect on logistics. Compounding this issue are the sharply rising costs associated with transportation and essential raw materials.

This strategic move is essential for the company to maintain operational stability and continue the supply of Liquid Rubber and ISOBAM amidst the volatile market conditions.